Thulium(3+);trifluoride

Base Information

• Chemical Name: Thulium(3+);trifluoride
• CAS No.: 13760-79-7
• Molecular Formula: TmF3
• Molecular Weight: 225.929
• Hs Code.: 2826199090
• Nikkaji Number: J134.251G
• Mol file: 13760-79-7.mol

Synonyms:14404-59-2;Thulium(3+);trifluoride;THULIUM FLUORIDE, 99.9per cent;Thulium(III)fluoride;F3Tm;F3-Tm;Tin chloride fluoride(SnClF) (7CI,8CI,9CI);Tin chloride fluoride (SnClF);AKOS025294441

Chemical Property of Thulium(3+);trifluoride

Chemical Property:

• Appearance/Colour: powder
• Melting Point: 1158oC
• Boiling Point: 19.5 °C at 760 mmHg
• Flash Point: 2200°C
• PSA: 0.00000
• Density: 7.9
• LogP: 1.26060
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 225.929428
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

97% ^*data from raw suppliers

Thulium(III) fluoride anhydrous, powder, 99.99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-32
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[Tm+3]
• Uses: Thulium(III) fluoride is used for glass doping, and used to enhance mid-IR emission in oxyfluoride glass ceramics. It is also used to improve ultraviolet and visible upconversion fluorescence in fluorinated glasses. ? ;Used for glass doping1? ;Used to enhance mid-IR emission in oxyfluoride glass ceramics2 DYSPROSIUM CHLORIDE has specialized uses in laser glass, phosphors and Dysprosium Metal halide lamp. Dysprosium is used in conjunction with Vanadium and other elements, in making laser materials and commercial lighting. Dysprosium is one of the components of Terfenol-D,which is employed in transducers, wide-band mechanical resonators, and high-precision liquid-fuel injectors.

Technology Process of Thulium(3+);trifluoride

There total 25 articles about Thulium(3+);trifluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thulia + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → thulium(III) fluoride (13760-79-7)

Guidance literature:

In neat (no solvent); byproducts: H2O; at elevated temp.;;

DOI:10.1021/ja02222a009 DOI:10.1007/BF01481992

Reference yield:

ammonium fluoride + thulia → thulium(III) fluoride (13760-79-7)

Guidance literature:

In hydrogenchloride; dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;

Reference yield:

chlorine trifluoride (7790-91-2) + thulia → thulium(III) fluoride (13760-79-7)

Guidance literature:

In neat (no solvent); at room temp. in presence of moisture;;

DOI:10.1021/ja01644a016

upstream raw materials:

sodium fluoride

xenon difluoride

chlorine trifluoride

thulium

Downstream raw materials:

thulium

terbium tetrafluoride

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