(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

Base Information

Chemical Name:(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid
CAS No.:125009-71-4
Molecular Formula:C₁₈H₂₆O₂
Molecular Weight:276.387
Hs Code.:

(E)-12-phenyl(2,3-<sup>(2)</sup>H<sub>2</sub>)dodec-2-enoic acid

Synonyms:(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

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Chemical Property of (E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

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Technology Process of (E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

There total 7 articles about (E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₈H₂₄⁽²⁾H₂O

: 125009-71-4
(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

Guidance literature:: With sodium chlorite; disodium hydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; for 2h; Yield given; Ambient temperature;
DOI:10.1002/hlca.19890720507

Reference yield:

: 629-03-8
1 ,6-dibromohexane

: 125009-71-4
(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 44 percent / Li₂CuCl₄ / tetrahydrofuran / Ambient temperature

2: 1.) BuLi / 1.) THF, room temperature, 15 min; 2.) HMPA, 40 deg C, overnight

3: 26.7 g / pyridinium p-toluenesulfonate / methanol / 0.5 h / Heating

4: 1.) LiAl⁽²⁾H₄; 2.) ⁽²⁾H₂O / 1.) THF, reflux, 30 min; 2.) 30 min

5: MnO₂ / CH₂Cl₂ / 1 h

6: NaClO₂, 2-methylbut-2-ene, Na₂HPO₄ / 2-methyl-propan-2-ol; H₂O / 2 h / Ambient temperature

With manganese(IV) oxide; sodium chlorite; disodium hydrogenphosphate; n-butyllithium; lithium aluminium deuteride; 2-methyl-but-2-ene; dilithium tetrachlorocuprate; ⁽²⁾H₂O; pyridinium p-toluenesulfonate; In tetrahydrofuran; methanol; dichloromethane; water; tert-butyl alcohol;
DOI:10.1002/hlca.19890720507

Reference yield:

: 1462-75-5
3-phenylpropylmagnesium bromide

: 125009-71-4
(E)-12-phenyl(2,3-⁽²⁾H₂)dodec-2-enoic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 44 percent / Li₂CuCl₄ / tetrahydrofuran / Ambient temperature

2: 1.) BuLi / 1.) THF, room temperature, 15 min; 2.) HMPA, 40 deg C, overnight

3: 26.7 g / pyridinium p-toluenesulfonate / methanol / 0.5 h / Heating

4: 1.) LiAl⁽²⁾H₄; 2.) ⁽²⁾H₂O / 1.) THF, reflux, 30 min; 2.) 30 min

5: MnO₂ / CH₂Cl₂ / 1 h

6: NaClO₂, 2-methylbut-2-ene, Na₂HPO₄ / 2-methyl-propan-2-ol; H₂O / 2 h / Ambient temperature

With manganese(IV) oxide; sodium chlorite; disodium hydrogenphosphate; n-butyllithium; lithium aluminium deuteride; 2-methyl-but-2-ene; dilithium tetrachlorocuprate; ⁽²⁾H₂O; pyridinium p-toluenesulfonate; In tetrahydrofuran; methanol; dichloromethane; water; tert-butyl alcohol;
DOI:10.1002/hlca.19890720507