Silane, ((1E)-1-butenyloxy)trimethyl-

Base Information

• Chemical Name: Silane, ((1E)-1-butenyloxy)trimethyl-
• CAS No.: 19980-23-5
• Molecular Formula: C7H16OSi
• Molecular Weight: 144.2868
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70885109
• Nikkaji Number: J422.051J,J601.208F
• Wikidata: Q82863731
• Mol file: 19980-23-5.mol

Synonyms:19980-23-5;Silane, ((1E)-1-butenyloxy)trimethyl-;[(E)-but-1-enoxy]-trimethylsilane;(E)-1-(Trimethylsiloxy)-1-butene;Silane, [(1E)-1-butenyloxy]trimethyl-;Silane, ((1E)-1-buten-1-yloxy)trimethyl-;Silane, [(1E)-1-buten-1-yloxy]trimethyl-;C7-H16-O-Si;1-(Trimethylsiloxy)-1-butene;SCHEMBL3382996;SCHEMBL10511347;DTXSID70885109;[(E)-1-Butenyloxy]trimethylsilane;Silane, (1-butenyloxy)trimethyl-, (E)-

Chemical Property of Silane, ((1E)-1-butenyloxy)trimethyl-

Chemical Property:

• Vapor Pressure: 13.7mmHg at 25°C
• Boiling Point: 127.1°Cat760mmHg
• Flash Point: 20.3°C
• PSA: 9.23000
• Density: 0.802g/cm³
• LogP: 2.76160
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 144.097041664
• Heavy Atom Count: 9
• Complexity: 91.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CO[Si](C)(C)C
• Isomeric SMILES: CC/C=C/O[Si](C)(C)C

Technology Process of Silane, ((1E)-1-butenyloxy)trimethyl-

There total 4 articles about Silane, ((1E)-1-butenyloxy)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + butyraldehyde (123-72-8) → 1-<(Trimethylsilyl)oxy>butene (19980-23-5) + Z-(1-buten-1-yloxy)trimethylsilane (19980-22-4)

Guidance literature:

With triethylamine; sodium bromide; In N,N-dimethyl-formamide; for 6h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

Reference yield:

chloro-trimethyl-silane (75-77-4) + butyraldehyde (123-72-8) → 1-<(Trimethylsilyl)oxy>butene (19980-23-5)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide;

DOI:10.1021/jo01260a018

Reference yield:

chloro-trimethyl-silane (75-77-4) + butyraldehyde (123-72-8) → (E)-1-phenyl-2-<(trimethylsilyl)oxy>propene (19980-25-7) + 1-<(Trimethylsilyl)oxy>butene (19980-23-5)

Guidance literature:

With triethylamine; sodium iodide; In acetonitrile; pentane; Yield given. Yields of byproduct given; 15 min, room temp.; 4 h, 40 deg C;

DOI:10.1016/S0040-4020(01)86789-2

upstream raw materials:

chloro-trimethyl-silane

butyraldehyde

Downstream raw materials:

(Z)-O-n-Butenyl S-phenyl thiocarbonate

(E)-O-n-Butenyl S-phenyl thiocarbonate

trans-1-phenyl-1-butene

(E)-2-Ethyl-4-iodo-5-(phenylsulfonyl)-4-pentenal