methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

Base Information

Chemical Name:methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate
CAS No.:133635-08-2
Molecular Formula:C₂₁H₂₈O₉
Molecular Weight:424.448
Hs Code.:

Synonyms:methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

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Chemical Property of methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

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Technology Process of methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

There total 5 articles about methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: methyl (methyl 3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

: 93-97-0
benzoic acid anhydride

: 133635-08-2
methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

Guidance literature:: With pyridine; dmap; at 35 ℃;

Reference yield:

: 111833-94-4
methyl 4-O-benzyl-3-deoxy-7,8-O-isopropylidene-α-D-manno-oct-2-ulopyrano-sidono-1,5-lactone

: 133635-08-2
methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

Guidance literature:: Multi-step reaction with 4 steps

1: methanol; CHCl₃ / 1 h

2: 91 percent / Ag₂O, CaSO₄ / 24 h / 35 °C / the methylation was repeated three times

3: 92 percent / H₂, 1percent methanolic NH₃ / 10percent Pd/C / ethyl acetate

4: 73 percent / pyridine, DMAP / 35 °C

With pyridine; dmap; calcium sulfate; ammonia; hydrogen; silver(l) oxide; palladium on activated charcoal; In methanol; chloroform; ethyl acetate;

Reference yield:

: 114729-36-1
(2R,4R,5R,6S)-4-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester

: 133635-08-2
methyl (methyl 4-O-benzoyl-3-deoxy-7,8-O-isopropylidene-5-O-methyl-α-D-manno-oct-2-ulopyranosid)onate

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Ag₂O, CaSO₄ / 24 h / 35 °C / the methylation was repeated three times

2: 92 percent / H₂, 1percent methanolic NH₃ / 10percent Pd/C / ethyl acetate

3: 73 percent / pyridine, DMAP / 35 °C

With pyridine; dmap; calcium sulfate; ammonia; hydrogen; silver(l) oxide; palladium on activated charcoal; In ethyl acetate;