{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

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Chemical Name:{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane
CAS No.:1258516-47-0
Molecular Formula:C₂₅H₃₆O₃Si
Molecular Weight:412.645
Hs Code.:

Synonyms:{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

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Chemical Property of {(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

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Technology Process of {(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

There total 11 articles about {(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1258516-46-9
(2S)-4-[4-(benzyloxy)phenyl]-1-[(2S)-oxiran-2-yl]butan-2-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1258516-47-0
{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃; for 5h;
DOI:10.1002/hlca.200900478

Reference yield: 48.0%

: 1638640-11-5
C₂₅H₃₆O₃Si

: 1258516-47-0
{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

: C₂₅H₃₈O₄Si

Guidance literature:: With (1S,2S)-N,N'-1,2-cyclohexylenebis(salicylideneaminato)cobalt(II); water; acetic acid; In toluene; at 0 - 20 ℃; for 16h;
DOI:10.1002/hlca.201300221

Reference yield:

: 1638640-10-4
C₂₃H₂₅NO₃

: 1258516-47-0
{(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane

: C₂₅H₃₈O₄Si

Guidance literature:: Multi-step reaction with 7 steps

1: copper(ll) sulfate pentahydrate / methanol / 0 - 20 °C

2: di(n-butyl)tin oxide; triethylamine / dichloromethane / 4 h / 0 - 20 °C

3: potassium carbonate / methanol / 1 h / 20 °C

4: copper(l) iodide / tetrahydrofuran / 1 h / -20 °C / Inert atmosphere

5: 1H-imidazole / dichloromethane / 4 h / 0 - 20 °C

6: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C

7: acetic acid; (1S,2S)-N,N'-1,2-cyclohexylenebis(salicylideneaminato)cobalt(II); water / toluene / 16 h / 0 - 20 °C

With 1H-imidazole; copper(l) iodide; copper(ll) sulfate pentahydrate; (1S,2S)-N,N'-1,2-cyclohexylenebis(salicylideneaminato)cobalt(II); water; di(n-butyl)tin oxide; potassium carbonate; acetic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1002/hlca.201300221