(2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

Base Information

• Chemical Name: (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester
• CAS No.: 80453-89-0
• Molecular Formula: C₂₂H₂₆O₆
• Molecular Weight: 386.445

Synonyms:(2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

Chemical Property of (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

There total 3 articles about (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(2E,4E,6E)-(8R,9S)-8-Hydroxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester (80453-93-6) + acetyl chloride (75-36-5) → (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester (80453-89-0)

Guidance literature:

With pyridine; In dichloromethane; at 0 ℃;

DOI:10.1016/S0040-4039(01)81931-6

Reference yield:

phenylacetic acid (103-82-2) → (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester (80453-89-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) THF, 0 deg C, 2.) THF, -20 deg C

2: 85 percent / C₅H₅N / CH₂Cl₂ / 0 °C

With pyridine; In dichloromethane;

DOI:10.1016/S0040-4039(01)81931-6

Reference yield:

2E,4E,6E-2,6-Dimethyl-7-ethoxycarbonyl-2,4,6-heptatrienal (63826-41-5) → (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester (80453-89-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) THF, 0 deg C, 2.) THF, -20 deg C

2: 85 percent / C₅H₅N / CH₂Cl₂ / 0 °C

With pyridine; In dichloromethane;

DOI:10.1016/S0040-4039(01)81931-6

upstream raw materials:

(2E,4E,6E)-(8R,9S)-8-Hydroxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

acetyl chloride

phenylacetic acid

2E,4E,6E-2,6-Dimethyl-7-ethoxycarbonyl-2,4,6-heptatrienal

Downstream raw materials:

ethyl (2E,4E,6E,8E)-3,7-dimethyl-9-phenylnona-2,4,6,8-tetraenoate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 80453-89-0 (2E,4E,6E)-(8S,9R)-8-Acetoxy-3,7-dimethyl-9-phenyl-deca-2,4,6-trienedioic acid 1-ethyl ester

Send

Send

Metric Ton KG G Pound L ML

Send

Send