[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

Base Information

Chemical Name:[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]
CAS No.:168064-07-1
Molecular Formula:C₃₆H₃₀ClPRu
Molecular Weight:630.131
Hs Code.:

Synonyms:[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

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Chemical Property of [(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

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Technology Process of [(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

There total 3 articles about [(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 908093-98-1
diazodiphenylmethane

: 168064-07-1
[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

Guidance literature:: In toluene; Ru complex and N2C(C6H5)2 were dissolved in C6H5CH3, the soln. was stirred at 65°C under Ar for 30 h (during this period, new N2C(C6H5)2was added after 10 h and 20 h); the soln. was concd., C7H16 was added, ppt. was sepd., crystd.(C6H5CH3/C7H16) and dried under vac.;
DOI:10.1021/om0003537

Reference yield: 62.0%

: [Ru(η(2)-O2CMe)(η(5)-C5H5)PPh3]

: 554-68-7
triethylamine hydrochloride

: 908093-98-1
diazodiphenylmethane

: 168064-07-1
[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

Guidance literature:: In toluene; Ar-atmosphere; stirring equimolar amts. of Ru-complex and Ph2CN2 (room temp., 5 min), evapn. (vac.), dissoln. in Me2CO, addn. of 1.5 equiv. Et3NHCl, stirring (room temp., 30 min); evapn. (vac.), extn. into PhMe, chromy. (Al2O3), evapn. (vac.), washing (pentane); elem. anal.;
DOI:10.1016/S0022-328X(97)00045-4

Reference yield: 51.0%

: [Ru(η(2)-O2CMe)(η(5)-C5H5)PPh3]

: 908093-98-1
diazodiphenylmethane

: 168064-07-1
[(η5-C5H5)Ru(P(C6H5)3)(C(C6H5)2)Cl]

Guidance literature:: In toluene; Ar-atmosphere; stirring equimolar amts. (room temp., 5 min); evapn. (vac.), dissoln. in PhMe, chromy. (Al2O3 contg. Cl(-)), evapn. (vac.), washing (pentane), drying (vac.);
DOI:10.1016/S0022-328X(97)00045-4