[η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

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Chemical Name:[η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt
CAS No.:912478-05-8
Molecular Formula:C₂₃H₁₇CoF₁₀N₆O₂P₆
Molecular Weight:844.247
Hs Code.:

Synonyms:[η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

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Chemical Property of [η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

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Technology Process of [η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

There total 2 articles about [η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: η5-carbomethoxycyclopentadienyl(η4-cyclooctadiene)cobalt

: 34671-22-2
(β-phenylethynyl)pentafluorocyclotriphosphazene

: 536-74-3
phenylacetylene

: 912478-05-8
[η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

: η5-carbomethoxycyclopentadienyl(η4-1-mono(pentafluorocyclotriphosphazene)-2,3-diphenyl-4a,5,6,9,10,10a-hexahydro[8]annulene)cobalt

Guidance literature:: In xylene; byproducts: 1,3,5-triphenylbenzene, 1,2,4-triphenylbenzene, (pentafluorocyclotriphosphazenyl)triphenylbenzene; under N2; soln. of Co complex, PhC2P3N3F5 and PhCCH in xylene refluxed for 33 h; solvent evapd.; column chromy. (silica gel, hexane to hexane/ethylacetate (6%)); elem. anal.;
DOI:10.1021/ic7024507

Reference yield: 11.0%

: 26305-75-9
chlorotris(triphenylphosphine)cobalt(I)

: 34671-22-2
(β-phenylethynyl)pentafluorocyclotriphosphazene

: sodium (methoxycarbonyl)cyclopentadienide

: 912478-05-8
[η5-carboxymethoxycyclopentadienyl][η4-1,3-bis(pentafluorocycltriphosphazenyl)-2,4-diphenylcyclobutadiene]cobalt

: 912478-04-7
(η5-carboxymethoxycyclopentadienyl)(triphenylphosphine)-2,4-bis(pentafluorocyclotriphosphazenyl)-3,5-diphenyl cobaltacyclopentadiene

: 912478-03-6
(η5-carboxymethoxycyclopentadienyl)(triphenylphosphine)-2,5-bis(pentafluorocyclotriphosphazenyl)-3,4-diphenyl cobaltacyclopentadiene

Guidance literature:: In tetrahydrofuran; toluene; byproducts: triphenylphosphine, triphenylphosphine oxide; (N2); addn. of a soln. of phosphorus compd. and cobalt complex in toluene to a soln. of ligand in THF, stirring at room temp. for 15 min, refluxfor 24 h; evapn., column chromy. (silica gel, hexane, then 2%, then 2.5%, then 3% ethyl acetate in hexane); elem. anal.;
DOI:10.1021/ic0609204