trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

Base Information

Chemical Name:trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)
CAS No.:945679-75-4
Molecular Formula:C₁₂₀H₁₃₂F₁₀P₄Pt₂
Molecular Weight:2278.41
Hs Code.:

trans,trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P(CH<sub>2</sub>)10CH=CH<sub>2</sub>)2Pt(C<sub>2</sub>)6Pt(Ph<sub>2</sub>P(CH<sub>2</sub>)10CH=CH<sub>2</sub>)2(C<sub>6</sub>F<sub>5</sub>)

Synonyms:trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

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Chemical Property of trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

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Technology Process of trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

There total 1 articles about trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 945679-74-3
trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)3SiEt₃

: 945679-75-4
trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

Guidance literature:: With catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; (C₄H₉)4NF; O₂; In tetrahydrofuran; water; acetone; diamine was added to CuCl in acetone, stirred for 0.5 h, (n-C4H9)4NF in THF/5 wt%H2O was added to a soln. of Pt-complex in acetone with stirring, after 20 min (CH3)3SiCl was added, O2 was bubbled, heated to 65°C, Cu-soln. was added over 4 h, 0.5h; the solvent was removed by oil pump vac.;
DOI:10.1021/ja071612n

Reference yield:

: 945679-75-4
trans,trans-(C₆F₅)(Ph₂P(CH₂)10CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)10CH=CH₂)2(C₆F₅)

: 1333-74-0
hydrogen

: 945679-77-6,945679-76-5
trans,trans-(C₆F₅)(Ph₂P-(CH₂)22PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)22PPh₂)(C₆F₅)

: 945679-76-5,945679-77-6
trans,trans-(C₆F₅)(Ph₂P-(CH₂)22PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)22PPh₂)(C₆F₅)

Guidance literature:: With catalyst: Pd/C; O₂; Grubbs catalyst first generation; In dichloromethane; 1. 5-7 mol% Grubbs' catalyst, CH2Cl2, 4 h refluxing; chromy., evapn.; 2.10% Pd/C, ClCH2CH2Cl, ethanol, 1 atm. of H2; chromy., 38% mixt. of complexes;
DOI:10.1021/ja071612n