Dibromo(triphenyl)-lambda~5~-bismuthane

Base Information

Chemical Name:Dibromo(triphenyl)-lambda~5~-bismuthane
CAS No.:7065-17-0
Molecular Formula:C₁₈H₁₅BiBr₂
Molecular Weight:600.106
Hs Code.:
NSC Number:173037
DSSTox Substance ID:DTXSID40305980

Synonyms:7065-17-0;Dibromo(triphenyl)-lambda~5~-bismuthane;NSC173037;triphenyl-bismuth dibromide;SCHEMBL3138026;DTXSID40305980;AKOS024432895;NSC-173037

Suppliers and Price of Dibromo(triphenyl)-lambda~5~-bismuthane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Dibromo(triphenyl)-lambda~5~-bismuthane

Chemical Property:

Vapor Pressure:4.21E-16mmHg at 25°C
Boiling Point:636.5°C at 760 mmHg
Flash Point:338.7°C
Density:1.36g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:599.93240
Heavy Atom Count:21
Complexity:285

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Bi](C2=CC=CC=C2)(C3=CC=CC=C3)(Br)Br

Technology Process of Dibromo(triphenyl)-lambda~5~-bismuthane

There total 13 articles about Dibromo(triphenyl)-lambda~5~-bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 153289-73-7
triphenylbismuth diformate

: 28719-55-3,7065-17-0
triphenylbismuth dibromide

Guidance literature:: With NaBr; In water; benzene; aq. NaBr soln. added in excess to soln. of the diformate in benzene; vigorous stirring for 10 min; sepn. of organic layer; drying (MgSO4); evapn. under reduced pressure gave crystals;

Reference yield: 79.0%

: {(C₆H₅)4Bi}⁽¹⁺⁾*Br₃^(1-)={(C₆H₅)4Bi}Br₃

: 28719-55-3,7065-17-0
triphenylbismuth dibromide

Guidance literature:: byproducts: C6H5Br; slow heating to 5°C in 15 h;

Reference yield: 40.0%

: 5324-13-0
2,6-dibromo-4-chlorophenol

: 603-33-8
triphenylbismuthane

: 28719-55-3,7065-17-0
dibromotriphenylbismuth

: 851392-40-0
bis(2,6-dibromo-4-chlorophenoxy)triphenylbismuth

Guidance literature:: With H₂O₂; In diethyl ether; water; byproducts: H2O; 2,6-dibromo-4-chlorophenol and 31% aq. soln. of H2O2 in Et2O were added to soln. of Ph3Bi in Et2O (molar ratio Ph3Bi, Br2ClC6H2OH, H2O2 was 1:2:1); kept at 20°C for 24 h; solvent removed; residue extd. (hexane); extd. vol. was reduced; soln. cooled to -18°C; crystals of Ph3Bi(OC6H2Br2Cl) were dried; residueextd. (toluene); toluene evapd.; Ph3BiBr was obtained;