triphenylbismuth diformate

Base Information

Chemical Name:triphenylbismuth diformate
CAS No.:153289-73-7
Molecular Formula:C₂₀H₁₇BiO₄
Molecular Weight:530.333
Hs Code.:

Synonyms:triphenylbismuth diformate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of triphenylbismuth diformate

Chemical Property:

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Technology Process of triphenylbismuth diformate

There total 7 articles about triphenylbismuth diformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 603-33-8
triphenylbismuthane

: 153289-73-7
triphenylbismuth diformate

: 28899-97-0,7239-60-3
triphenylbismuth(V) diacetate

Guidance literature:: With ozone; toluene; In toluene; ozonized oxygen passed into toluene for 1 h at -78°C: green soln.; BiPh3 in toluene added: yellow suspn.; warmed to ambient temp. while being flushed with Ar: yellow soln.; react. mechanism discussed; evapn. under reduced pressure; recrystn. of residue (contg. also the diacetate) from benzene/hexane gave crystals of the pure diformate; elem. anal.;

Reference yield: 80.0%

: 64-18-6
formic acid

: 603-33-8
triphenylbismuthane

: 153289-73-7
triphenylbismuth diformate

Guidance literature:: With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH (5 mmol) was added dropwise to a stirred cold (5-10°C) soln. of Ph3Bi (5 mmol) and HCOOH (10 mmol) in Et2O; the mixt. was kept inthe dark for 24 h at room temp.; the solvent was distd. off under reduced pressure; purifn. by recrystn. (CHCl3/hexane);
DOI:10.1016/j.jorganchem.2005.04.051

Reference yield: 40.0%

: 603-33-8
triphenylbismuthane

: triphenylbismuthine carbonate

: 153289-73-7
triphenylbismuth diformate

Guidance literature:: With ozone; carbon dioxide; toluene; In toluene; Ph3Bi and solid CO2 mixed in toluene, through which was passed ozonized oxygen for 1 h at -78°C; react. mechanism discussed; resulting suspn. filtered to remove Ph3BiCO3; filtrate evapd. in vac.; residue washed with cold hexane to give Ph3Bi(OCHO)2; combined hexane washings evapd. to give recovery of Ph3Bi (35%);