phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Base Information

Chemical Name:phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside
CAS No.:400737-62-4
Molecular Formula:C₁₉H₃₂O₄SSi
Molecular Weight:384.612
Hs Code.:

Synonyms:phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Suppliers and Price of phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

There total 4 articles about phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 327603-45-2
phenyl 4-O-methyl-1-thio-α-L-rhamnopyranoside

: 400737-62-4
phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 - 25 ℃; for 3h;
DOI:10.1002/1521-3773(20011015)40:20<3849::AID-ANIE3849>3.0.CO;2-M

Reference yield: 91.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 327603-45-2
phenyl 4-O-methyl-1-thio-α-L-rhamnopyranoside

: 400737-62-4
phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane;
DOI:10.1002/anie.200460172

Reference yield:

: 131087-35-9
phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

: 400737-62-4
phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / KOH / dimethylformamide / 2 h / 0 °C

2: 89 percent / p-TsOH / dimethylformamide / 6 h / 20 °C

3: 91 percent / imidazole; DMAP / CH₂Cl₂; toluene / 16 h / 20 °C

With 1H-imidazole; dmap; potassium hydroxide; toluene-4-sulfonic acid; In dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/chem.200600462