(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

Base Information

Chemical Name:(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane
CAS No.:1273299-31-2
Molecular Formula:C₂₃H₃₀O₂Si
Molecular Weight:366.576
Hs Code.:

Synonyms:(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

Suppliers and Price of (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

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Technology Process of (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

There total 1 articles about (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 3536-96-7
vinylmagnesium chloride

: 408348-31-2
(1R,2R)-2-(tert-butyldiphenylsilyloxy)methyl-1-formylcyclopropane

: 1273299-31-2
(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

Guidance literature:: In tetrahydrofuran; at 0 ℃; for 2h; Inert atmosphere;
DOI:10.1039/c0ob00597e

Reference yield:

: 1273299-31-2
(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

: 695-84-1
2-allylphenol

: 1273299-58-3
(1R,2R)-1-(benzofuran-2-yl)-2-t-butyldiphenylsilyloxymethylcyclopropane

Guidance literature:: (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane; 2-allylphenol; With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

With carbonylchlorohydridotris(triphenylphosphine)ruthenium (II); In 5,5-dimethyl-1,3-cyclohexadiene; at 20 ℃; for 14h;

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In 5,5-dimethyl-1,3-cyclohexadiene; at 80 ℃; for 2h;
DOI:10.1039/c0ob00597e

Reference yield:

: 1273299-31-2
(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane

: 695-84-1
2-allylphenol

: 1273299-52-7
(1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-(2H-chromen-2-yl)cyclopropane

Guidance literature:: (1R,2R)-2-t-butyldiphenylsilyloxymethyl-1-[1-hydroxyprop-2-en-1-yl]cyclopropane; 2-allylphenol; With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In toluene; at 20 ℃; Reflux; Inert atmosphere;
DOI:10.1039/c0ob00597e