(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH)

Base Information

• Chemical Name: (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH)
• CAS No.: 135139-68-3
• Molecular Formula: C₃₆H₇₂OSSi₇
• Molecular Weight: 749.632
• Mol file: 135139-68-3.mol

Synonyms:(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH)

Chemical Property of (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH)

There total 8 articles about (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-(2,4,6-trimethylphenyl)silanedithiol (1005519-97-0) → (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH) (135139-68-3)

Guidance literature:

With water; silica gel; In hexane;

DOI:10.1002/ejic.200601226

Reference yield: 4.0%

(CH3)3C6H2[((CH3)3Si)2CH]3C6H2SiH2 (135139-77-4) → (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH) (135139-68-3)

Guidance literature:

With sulfur; at 300 ℃; for 0.166667h;

Reference yield:

(Z)-1,2-dimesityl-1,2-bis{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}disilene → (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(SH)(OH) (135139-68-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: Cp₂ZrS₅ / tetrahydrofuran / 20 h / 60 °C

1.2: 41 percent / water / tetrahydrofuran; benzene

2.1: 93 percent / water; SiO₂ / hexane

With water; silica gel; In tetrahydrofuran; hexane;

DOI:10.1002/ejic.200601226

upstream raw materials:

(CH₃)3C₆H₂[((CH₃)3Si)2CH]3C₆H₂SiH₂

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-(2,4,6-trimethylphenyl)silanedithiol

1,2,3,4,5-tetrathiasilolane

mesityllithium

Downstream raw materials:

[(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)(2,4,6-trimethylphenyl)Si(μ-S)(μ-O)Ru(η6-benzene)]

[(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(mesityl)Si(μ-O)(μ-S)Pt(triphenylphosphine)2]