3,6-DICHLOROCARBAZOLE

Base Information

• Chemical Name: 3,6-DICHLOROCARBAZOLE
• CAS No.: 5599-71-3
• Molecular Formula: C12H7 Cl2 N
• Molecular Weight: 236.1
• Mol file: 5599-71-3.mol

Synonyms:Carbazole,3,6-dichloro- (6CI,7CI,8CI); 3,6-Dichlorocarbazole; NSC 39031

Chemical Property of 3,6-DICHLOROCARBAZOLE

Chemical Property:

• Vapor Pressure: 7.11E-07mmHg at 25°C
• Melting Point: 207-208
• Boiling Point: 420°Cat760mmHg
• PKA: 15.52±0.30(Predicted)
• Flash Point: 240.3°C
• PSA: 15.79000
• Density: 1.476g/cm³
• LogP: 4.62790
• Solubility.: soluble in Acetone

Purity/Quality:

99% ^*data from raw suppliers

3,6-Dichloro-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,6-DICHLOROCARBAZOLE

There total 3 articles about 3,6-DICHLOROCARBAZOLE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C20H19Cl2N2(1+)*BF4(1-) → 3,6-dichloro-9H-carbazole (5599-71-3) + bis(4-chlorophenyl)amine (6962-04-5) + (4-chloro-phenyl)-(2,4-dichloro-phenyl)-amine (817194-11-9)

Guidance literature:

With sodium chloride; In acetonitrile; Photolysis;

DOI:10.1021/jo062578i

Reference yield:

N-chlorocarbazole (105598-33-2) → 1,6-dichlorocarbazole (64389-47-5) + 1-chlorocarbazole (5599-70-2) + 3,6-dichloro-9H-carbazole (5599-71-3) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1)

Guidance literature:

In methanol; at 39 ℃;

DOI:10.1002/jhet.5570340327

Reference yield:

N-chlorocarbazole (105598-33-2) → 1,6-dichlorocarbazole (64389-47-5) + 1-chlorocarbazole (5599-70-2) + 3-chloro-9H-carbazole (2732-25-4) + 3,6-dichloro-9H-carbazole (5599-71-3) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1)

Guidance literature:

In methanol; dichloromethane; for 1h; Product distribution; Mechanism; Heating; var. times, also in the presence of acid or basic reaction partner;

DOI:10.1021/jo00378a002

upstream raw materials:

N-chlorocarbazole

Downstream raw materials:

3,6-dichloro-N-benzoylcarbazole

3,6-dichloro-1-nitrocarbazole

3,6-dichloro-9-(1-phenylvinyl)-9H-carbazole

Refernces

• 1、 Bonesi, Sergio M.,Erra-Balsells, Rosa. "On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of Carbazoles". . p. 877 - 889. Retrieved 2007/10/03.