6962-04-5

Basic information

• Product Name: Bis(4-chlorophenyl)amine
• Synonyms: Bis(4-chlorophenyl)amine
• CAS NO: 6962-04-5
• Molecular Formula: C₁₂H₉Cl₂N
• Molecular Weight: 238.11
• Mol File: 6962-04-5.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 348.4°C at 760 mmHg
• Flash Point: 164.5°C
• Appearance: /
• Density: 1.327g/cm³
• Vapor Pressure: 5.03E-05mmHg at 25°C
• Refractive Index: 1.649
• CAS DataBase Reference: Bis(4-chlorophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-chlorophenyl)amine(6962-04-5)
• EPA Substance Registry System: Bis(4-chlorophenyl)amine(6962-04-5)

Safety Data

• Hazardous Substances Data: 6962-04-5(Hazardous Substances Data)

Usage

General Description

Bis(4-chlorophenyl)amine is a synthetic organic compound that is composed of two chlorobenzene groups linked by an amine (-NH2) group. It is used extensively in the manufacturing of dyes and polymers. Its chemical formula is C12H9Cl2N, which indicates it consists of twelve carbon atoms, nine hydrogen atoms, two chlorine atoms, and one nitrogen atom. It is known to be a commonly used compound in organic chemistry due to its stability and versatility in chemical reactions. Despite its wide usage, proper caution should be exercised by those handling bis(4-chlorophenyl)amine as it can be harmful if ingested or inhaled, and may cause eye or skin irritation.

InChI:InChI=1/C12H9Cl2N/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8,15H

Upstream product

• 122-39-4 diphenylamine 
• 71-43-2 benzene 
• 1073-69-4 N-4-chlorophenylhydrazine 
• 106-47-8 4-chloro-aniline 
• 74-11-3 para-chlorobenzoic acid 
• 106-39-8 bromochlorobenzene 
• 1679-18-1 4-Chlorophenylboronic acid 
• 637-87-6 1-Chloro-4-iodobenzene 
• 68-12-2 N,N-dimethyl-formamide 
• 4051-56-3 N,N-diphenylbenzamide 
• 27779-01-7 diphenylcyanamide 
• 91961-82-9 1,1-di(4-chlorophenyl)hydrazine 
• 621-23-8 1,2,3-trimethoxybenzene 
• 539-03-7 N-(4-chlorophenyl)acetamide 

Downstream Products

• 1449692-63-0 2-[4-(di-p-chlorophenylamino)phenyl]pyridine 
• 1581259-03-1 ethyl 2-[N,N-bis(4-chlorophenyl)sulfamoyl]-2-diazoacetate 
• 1581258-79-8 ethyl 5-chloro-1-(4-chlorophenyl)-1,3-dihydrobenzo[c]isothiazole-3-carboxylate 2,2-dioxide 
• 1581259-51-9 ethyl 2-[N,N-bis(4-chlorophenyl)sulfamoyl]acetate 
• 59501-34-7 4,4'-dichlorodiphenylnitrosamine 

Relevant articles and documents

Emission-Tunable Soft Porous Organic Crystal Based on Squaraine for Single-Crystal Analysis of Guest-Induced Gate-Opening Transformation

Soft porous crystals (SPCs) with both crystallinity and flexibility have evolved as emerging materials for lots of applications. However, the development of purely organic SPCs (SPOCs) with advanced functionalities significantly lags behind. Herein, we report the construction of an emission-tunable SPOC with a rationally designed squaraine derivative (named as SPOC-SQ). SPOC-SQ is featured with a squaraine core and four peripheries with electron donor-π-acceptor (D-π-A) characteristics, which facilitates the formation of porous crystal framework stabilized by π-πinteractions and H bonds and at the same time provides structural flexibility through phenyl rotations. This SPOC can be easily obtained from its dichloromethane (DCM) solution and exhibits reversible stimuli-responsive single-crystal-to-single-crystal (SCSC) structural transformation, accompanied by bright and tunable emission. In addition, this activated SPOC (SPOC-SQ-a) selectively recognizes and absorbs acetylene (C2H2) over other gases without destroying the single crystallinity, enabling the single-crystal XRD analysis of the structural transformation. Close inspection of single-crystal XRD results of SPOC-SQ-C2H2 facilitates the understanding of the host-guest interactions. More interestingly, upon interacting with C2H2, a one-dimensional (1D) channel is formed in the crystal to adopt C2H2, which proves the SCSC process and provides molecular-level insights into the gate-opening process. Furthermore, C2H2 adsorption dynamics can be monitored in real time by tracking the fluorescence wavelength changes of SPOC-SQ framework. Thus, the unique gate-opening sorption attribute of SPOC-SQ-a crystals toward C2H2 enables its potential applications for gas separation.

Copper complexes of 1,4-diazabutadiene ligands: Tuning of metal oxidation state and, application in catalytic C-C and C-N bond formation

Reaction of 1,4-diazabutadiene (p-RC6H4N = C(H)(H)C = NC6H4R-p; R = OCH3, CH3, H and Cl; abbreviated as L-R) with CuCl2·2H2O in methanol at ambient temperature (25 °C) affords a group of doubly chloro-bridged dicopper complexes of type [{CuI(L-R)Cl}2], designated as 1-R. Similar reaction carried out in acetonitrile furnishes a family of doubly chloro-bridged dicopper complexes of type [{CuII(L-R)Cl2}2], designated as 2-R. Molecular structures of 1-OCH3 and 2-OCH3 have been determined by X-ray crystallography. While copper(I) is having a nearly tetrahedral N2Cl2 coordination sphere in 1-OCH3, the N2Cl3 coordination sphere around copper(II) is distorted square pyramidal in nature in 2-OCH3. Isolated 2-R complexes, on dissolution in methanol, are found to undergo facile reduction of the metal center to generate the corresponding 1-R complexes. The 1-R and 2-R complexes show intense absorptions in the visible and ultraviolet regions. Cyclic voltammetry on the 1-R and 2-R complexes shows both metal-centered and ligand centered redox responses. The 1-R complexes are found to efficiently catalyze C-N cross-coupling reactions between arylboronic acids and aryl amines; while the 2-R complexes display notable catalytic efficiency for nitroaldol reactions.

Tuning the Photophysical Properties of Symmetric Squarylium Dyes: Investigation on the Halogen Modulation Effects

A series of symmetric squarylium dyes (SQDPA-X) with different halogen (X=F, Cl, Br, I) substituents have been developed. The photophysical properties could be facilely tuned by the halogen modulation effects. The strategy of incorporating different halogen substitutions into AIE active luminogens enables a facile approach for exploring new intriguing organic fluorescent dyes.