(S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

Base Information

Chemical Name:(S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene
CAS No.:74286-48-9
Molecular Formula:C₂₈H₃₄FeNPSi
Molecular Weight:499.491
Hs Code.:

Synonyms:(S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

Suppliers and Price of (S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

There total 1 articles about (S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 75-77-4
chloro-trimethyl-silane

: 74311-51-6,33085-32-4,61116-64-1
(Spl)-2-(1-N,N-dimethylaminomethyl)-1-diphenylphosphinoferrocene

: 74286-48-9
(S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; addition of BuLi in hexane to a soln. of complex, stirred at room temperature for 1.5 h, addition of ClSiMe3 with gentle reflux, refluxed for 2h, N2 atm.; addition of water and aq. NaOH, extn. (benzene), washing with brine, drying over Na2SO4, evapn., column chromy. (alumina, benzene/ether 1/1);
DOI:10.1246/bcsj.53.1138

Reference yield:

: 74286-48-9
(S)-1-diphenylphosphino-2-dimethylaminomethyl-3-(trimethylsilyl)ferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 409095-06-3,74286-14-9
(S)-1',1-bis(diphenylphosphino)-2-(dimethylaminomethyl)ferrocene

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In diethyl ether; hexane; addition of BuLi in hexane and TMEDA to a soln. of complex, addition ofClPPh2 at 0°C to a stirred mixture, refluxed for 1.5 h, N2 atm.; addition of 30% NaOH at 0°C, extn. (benzene), washing with brine, drying over Na2SO4, evapn., column chromy. (alumina, hexane/benzene 1/1), treatment with t-BuOK in DMSO, preparative TLC (silica gel, benzene/acetone 1/1); elem. anal.;
DOI:10.1246/bcsj.53.1138