(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

Base Information

Chemical Name:(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate
CAS No.:244260-85-3
Molecular Formula:C₃₃H₄₀O₅Si
Molecular Weight:544.763
Hs Code.:

Synonyms:(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

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Chemical Property of (1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

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Technology Process of (1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

There total 3 articles about (1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 244260-84-2
(E)-(2S,3S)-2-But-3-enyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-(4-methoxy-benzyloxy)-hex-4-enoic acid methyl ester

: 244260-85-3
(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

Guidance literature:: Grubbs catalyst first generation; In dichloromethane; for 0.5h; Yield given; Heating;
DOI:10.1016/S0040-4039(99)00912-0

Reference yield:

: (E)-(2S,3S)-2-But-3-enyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-(4-methoxy-benzyloxy)-hex-4-enoic acid

: 244260-85-3
(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether / 0.5 h / Ambient temperature

2: Grubbs catalyst / CH₂Cl₂ / 0.5 h / Heating

Grubbs catalyst first generation; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(99)00912-0

Reference yield:

: (S)-2-[(S)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-allyl]-2-(4-methoxy-benzyloxy)-hex-5-enoic acid

: 244260-85-3
(1S,2S) methyl 2-([tert-butyl(diphenyl)silyloxy]methyl)-1-(4-methoxybenzyloxy)cyclohex-3-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / second generation Grubbs catalyst / CH₂Cl₂ / 1 h / 40 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane;
DOI:10.1016/j.tetasy.2004.12.029