Technology Process of methyl 12-benzoyloxypodocarpa-8,11,13-trien-19-oate
There total 7 articles about methyl 12-benzoyloxypodocarpa-8,11,13-trien-19-oate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine;
at 100 ℃;
for 5h;
-
-
55025-16-6
methyl (1S,4aS,10aR)-6-(benzyloxy)-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 84 percent / chromium trioxide, acetic acid / 22 h
2: 91 percent / sodium borohydride / tetrahydrofuran; H2O / 24 h
3: 81 percent / HCl / methanol / 5 h / Heating
4: 1.) borane, dimethyl sulfide, 2.) H2O2, sodium hydroxide / 1.) THF, 3.5 h, 2.) THF, water, 50 deg, 1 h
5: 80 percent / ammonium formate / 10percent Pd/C
6: 79 percent / pyridine / 5 h / 100 °C
With
pyridine; chromium(VI) oxide; hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; dimethylsulfide; borane; dihydrogen peroxide; ammonium formate; acetic acid;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; water;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 91 percent / sodium borohydride / tetrahydrofuran; H2O / 24 h
2: 81 percent / HCl / methanol / 5 h / Heating
3: 1.) borane, dimethyl sulfide, 2.) H2O2, sodium hydroxide / 1.) THF, 3.5 h, 2.) THF, water, 50 deg, 1 h
4: 80 percent / ammonium formate / 10percent Pd/C
5: 79 percent / pyridine / 5 h / 100 °C
With
pyridine; hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; dimethylsulfide; borane; dihydrogen peroxide; ammonium formate;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; water;
