(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

Base Information

Chemical Name:(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine
CAS No.:853803-99-3
Molecular Formula:C₃₄H₄₃NO₃Si
Molecular Weight:541.806
Hs Code.:

Synonyms:(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

Suppliers and Price of (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

Chemical Property:

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Technology Process of (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

There total 1 articles about (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 239466-40-1
ethyl (E)-2-(4-hydroxy-1-tritylpiperidin-3-ylidene)acetate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 853803-99-3
(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide; at 20 ℃; Cooling with ice;

Reference yield: 95.0%

: 853803-99-3
(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

: 853804-01-0
(E)-4-(t-butyldimethylsilyloxy)-3-(2-hydroxyethylidene)-1-(triphenylmethyl)piperidine

Guidance literature:: (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine; With diisobutylaluminium hydride; In dichloromethane; toluene; at -70 ℃; for 3h;

With water; ammonium chloride; In dichloromethane; toluene;

Reference yield: 69.0%

: 853803-99-3
(E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine

: 74-88-4
methyl iodide

: 916084-00-9
4-(t-butyldimethylsilyloxy)-3-[(1-ethoxycarbonyl)ethylidene]-1-(triphenylmethyl)piperidine

Guidance literature:: (E)-4-(t-butyldimethylsilyloxy)-3-[(ethoxycarbonyl)methylidene]-1-(triphenylmethyl)piperidine; With lithium diisopropyl amide; In tetrahydrofuran; n-heptane; ethylbenzene; at -78 ℃; for 1h;

methyl iodide; In tetrahydrofuran; n-heptane; ethylbenzene; at -78 - 20 ℃;