2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Base Information

Chemical Name:2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester
CAS No.:314041-41-3
Molecular Formula:C₂₃H₃₀O₃
Molecular Weight:354.489
Hs Code.:

Synonyms:2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Suppliers and Price of 2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of 2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

There total 6 articles about 2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2977-45-9
2,2-dimethyl-3,4-dihydro-2H-naphthalen-1-one

: 314041-41-3
2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: t-butylhydroperoxide; chromic oxide / CH₂Cl₂; H₂O / 96 h

2.1: LDA / tetrahydrofuran / 1.5 h / -78 °C

2.2: tetrahydrofuran / 2 h / 20 °C

3.1: triphenylphosphine; diisopropylethylamine / Pd(OAc)2 / dimethylformamide

With chromium(VI) oxide; tert.-butylhydroperoxide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; lithium diisopropyl amide; palladium diacetate; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1039/b702572f

Reference yield:

: 254981-70-9
2,2-dimethyl-2,3-dihydronaphthalene-1,4-dione

: 314041-41-3
2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 1.5 h / -78 °C

1.2: tetrahydrofuran / 2 h / 20 °C

2.1: triphenylphosphine; diisopropylethylamine / Pd(OAc)2 / dimethylformamide

With N-ethyl-N,N-diisopropylamine; triphenylphosphine; lithium diisopropyl amide; palladium diacetate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1039/b702572f

Reference yield:

: 254981-71-0
C₁₃H₁₁F₃O₄S

: 314041-41-3
2,2-dimethyl-1,2-dihydronaphthalenone-4-carboxylic acid (+)-menthyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.33 g / triphenylphosphine; diisopropylethylamine / Pd(OAc)2 / dimethylformamide / 9 h

2: aq. LiOH / methanol

3: EDC; 4-dimethylaminopyridine

With dmap; lithium hydroxide; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; palladium diacetate; In methanol; N,N-dimethyl-formamide;
DOI:10.1039/b702572f