CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)

Base Information

• Chemical Name: CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)
• CAS No.: 262611-70-1
• Molecular Formula: C₃₇H₃₇N₅O₄SZn
• Molecular Weight: 713.188

Synonyms:CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)

Chemical Property of CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)

There total 2 articles about CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[ethyl-(14RS)-(14-cyano-12,13,14,17-tetrahydro-2,3,8,13,13,14-heptamethyl-15H-tripyrrin-1-carboxylato)]nickel(II) (79826-88-3) + zinc diacetate (557-34-6) + Benzyl-(6-formyl-3,5-dihydro-1H-thieno[3,4-c]pyrrol-4-carboxylat)-2,2-dioxid (262611-68-7) → CH3C(CN)C(CH3)2CH2C(NZn(NC(C(CH3))2C))(CHC(NC(OCOCH2C6H5)C2)(CH2)2SO2)CHC(NC(C(CH3))2CH) (262611-70-1)

Guidance literature:

With potassium hydroxide; In chloroform; 1.) Ni complex, 5N KOH, MeOH/H2O (9/1), THF, reflux, 45 min; 2.) the pyrrolaldehyde (1.8 equiv.), p-TsOH, CHCl3, reflux, 30 min; Zn acetate, NaOAc, ambient temp., 20 min.; chromy.;

Reference yield:

benzyl 20-cyano-1,3,18,19,20,24-hexahydro-8,9,13,14,19,19,20-heptamethyl-22H-thieno[3,4-b]biline-4-carboxylate 2,2-dioxide (262611-69-8) + zinc diacetate (557-34-6) → [benzyl 20-cyano-1,3,18,19,20,24-hexahydro-8,9,13,14,19,19,20-heptamethyl-22H-thieno[3,4-b]biline-4-carboxylate 2,2-dioxidato(2-)-κN21,κN22,.kaapa.N23,κN24]zinc(II) (262611-70-1)

Guidance literature:

With sodium acetate; In methanol; dichloromethane; treatment of CH2Cl2 soln. of the bilin with MeOH soln. of Zn(OAc)2 and NaOAc, 35 min stirring at room temp. under Ar, addn. to satd. NaHCO3 soln.; extn. with CH2Cl2, filtration, evapn., chromy. (Alox, CH2Cl2/AcOEt 19:1), recrystn. from CH2Cl2/pentane;

DOI:10.1002/1522-2675(20000906)83:9<2231::AID-HLCA2231>3.0.CO;2-S

upstream raw materials:

benzyl 20-cyano-1,3,18,19,20,24-hexahydro-8,9,13,14,19,19,20-heptamethyl-22H-thieno[3,4-b]biline-4-carboxylate 2,2-dioxide

zinc diacetate

[ethyl-(14RS)-(14-cyano-12,13,14,17-tetrahydro-2,3,8,13,13,14-heptamethyl-15H-tripyrrin-1-carboxylato)]nickel(II)

Benzyl-(6-formyl-3,5-dihydro-1H-thieno[3,4-c]pyrrol-4-carboxylat)-2,2-dioxid

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 262611-70-1 CH₃C(CN)C(CH₃)2CH₂C(NZn(NC(C(CH₃))2C))(CHC(NC(OCOCH₂C₆H₅)C₂)(CH₂)2SO₂)CHC(NC(C(CH₃))2CH)

Send

Send

Metric Ton KG G Pound L ML

Send

Send