{[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Base Information

• Chemical Name: {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene
• CAS No.: 889654-24-4
• Molecular Formula: C₁₈H₃₂OSi₂
• Molecular Weight: 320.622
• Mol file: 889654-24-4.mol

Synonyms:{[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Chemical Property of {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

There total 2 articles about {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-1-(phenyldimethylsilyl)-2-buten-1-ol (96720-38-6) + tert-butyldimethylsilyl chloride (18162-48-6) → {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene (889654-24-4)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; at 23 ℃;

DOI:10.1021/ol060596g

Reference yield:

phenyldimethylsilyl chloride (768-33-2) → {[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene (889654-24-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: lithium / tetrahydrofuran / 18 h / 24 °C

1.2: tetrahydrofuran / 0.33 h / -78 °C

2.1: 5.86 g / imidazole / dimethylformamide / 12 h / 23 °C

With 1H-imidazole; lithium; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1021/jo070634p

Reference yield: 84.0%

{[1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene (889654-24-4) → C18H32OSi2 (949094-58-0)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 3h;

DOI:10.1021/jo070634p

upstream raw materials:

(E)-1-(phenyldimethylsilyl)-2-buten-1-ol

tert-butyldimethylsilyl chloride

phenyldimethylsilyl chloride

Downstream raw materials:

C₁₈H₃₂OSi₂

(+/-)-(E)-(1-dimethylphenylsilyl-1-buten-3-yl) pivalate

(E)-(±)-1-(dimethylphenylsilyl)-1-buten-3-ol