Bis(2-aminophenolato-N,O)copper

Base Information

• Chemical Name: Bis(2-aminophenolato-N,O)copper
• CAS No.: 18347-30-3
• Molecular Formula: C12H12CuN2O2
• Molecular Weight: 279.785
• European Community (EC) Number: 242-224-3
• Mol file: 18347-30-3.mol

Synonyms:EINECS 242-224-3;18347-30-3;Bis(2-aminophenolato-N,O)copper;NSC 4125

Chemical Property of Bis(2-aminophenolato-N,O)copper

Chemical Property:

• Vapor Pressure: 0.0345mmHg at 25°C
• Boiling Point: 234.5°Cat760mmHg
• Flash Point: 95.6°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 279.019475
• Heavy Atom Count: 17
• Complexity: 74.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)N)[O-].C1=CC=C(C(=C1)N)[O-].[Cu+2]

Technology Process of Bis(2-aminophenolato-N,O)copper

There total 7 articles about Bis(2-aminophenolato-N,O)copper which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper diacetate (142-71-2) + 2-amino-phenol (95-55-6) → Cu(2-aminophenolate)2 (18347-30-3)

Guidance literature:

2-amino-phenol; With triethylamine; In ethanol; for 1h; Reflux;

copper diacetate; In ethanol; for 24h; Reflux;

DOI:10.1007/s11164-018-3484-z

Reference yield:

copper(II) ion + 2-amino-phenol (95-55-6) → Cu(2-aminophenolate)2 (18347-30-3)

Guidance literature:

With sodium hydroxide; In ethanol; water; mixing of 1% alc. soln. of 2-aminophenol and a soln. of Cu(II)-salt; addn. of NaOH;; ppt.;;

DOI:10.1021/ja01126a007

Reference yield:

2-amino-phenol (95-55-6) → Cu(2-aminophenolate)2 (18347-30-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Fehling soln.; H₂O / water

2: neat (no solvent)

With Fehling soln.; H₂O; In water;

upstream raw materials:

2-amino-phenol

copper(II) sulfate

{Cu(OC₆H₄NH₂)2}*H₂O

copper diacetate

Downstream raw materials:

2-amino-phenol