9-Fluorenyl acetate

Base Information

• Chemical Name: 9-Fluorenyl acetate
• CAS No.: 25017-68-9
• Molecular Formula: C15H12O2
• Molecular Weight: 224.259
• Hs Code.: 2915390090
• DSSTox Substance ID: DTXSID40179729
• Nikkaji Number: J104.562H
• Wikidata: Q83050256
• Mol file: 25017-68-9.mol

Synonyms:9-Fluorenyl acetate;25017-68-9;9H-Fluoren-9-yl acetate;Fluoren-9-ol, acetate;9H-Fluoren-9-ol, acetate;9H-fluoren-9-yl ethanoate;Fluorenyl acetate;9-Acetoxyfluorene;9H-Fluoren-9-ylacetate;9H-Fluoren-9-yl acetate #;SCHEMBL4402923;DTXSID40179729;UWSLPNWPRYFAMX-UHFFFAOYSA-N;acetic acid 9H-fluoren-9-yl ester;MFCD00016354;AKOS015837878;FT-0621657;A817606

Chemical Property of 9-Fluorenyl acetate

Chemical Property:

• Vapor Pressure: 3.68E-05mmHg at 25°C
• Melting Point: 69.5 °C
• Boiling Point: 353.1°C at 760 mmHg
• Flash Point: 161°C
• PSA: 26.30000
• Density: 1.21g/cm³
• LogP: 3.31950
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 224.083729621
• Heavy Atom Count: 17
• Complexity: 277

Purity/Quality:

97% ^*data from raw suppliers

9-FluorenylAcetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=O)OC1C2=CC=CC=C2C3=CC=CC=C13

Technology Process of 9-Fluorenyl acetate

There total 4 articles about 9-Fluorenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

9H-fluorene (86-73-7) + Mangantriacetat → 9-acetoxy-9H-fluorene (25017-68-9) + 4,4'-Dimethoxybenzhydrol (728-87-0)

Guidance literature:

With *5H2O; lithium chloride; In acetic acid; for 2h; Heating;

DOI:10.1246/bcsj.62.3567

Reference yield: 8.0%

9H-fluorene (86-73-7) + sodium acetate (127-09-3) → 9,9-dibromo-9H-fluorene (15300-75-1) + 9-acetoxy-9H-fluorene (25017-68-9)

Guidance literature:

With dipotassium peroxodisulfate; lithium bromide; In acetic acid; at 113 ℃; for 6h;

DOI:10.1021/jo00231a017

Reference yield:

9H-fluorene (86-73-7) + acetic acid (64-19-7,77671-22-8) → 9-fluorenone (486-25-9,952573-42-1) + 9-acetoxy-9H-fluorene (25017-68-9)

Guidance literature:

With sodium nitrate; H₅PV₂Mo₁₀O₄₀; at 80 ℃; for 14h;

DOI:10.1021/ja031710i

upstream raw materials:

9H-fluorene

sodium acetate

9-fluorenone

acetic acid

Downstream raw materials:

9-Fluorenol

ethyl acetate

9H-fluorene

9-methylfluorene