{(NP₃)RhCl₂}BPh₄

Base Information

Chemical Name:{(NP₃)RhCl₂}BPh₄
CAS No.:85233-87-0
Molecular Formula:C₂₄H₂₀B*C₄₂H₄₂Cl₂NP₃Rh
Molecular Weight:1146.77
Hs Code.:

{(NP<sub>3</sub>)RhCl<sub>2</sub>}BPh<sub>4</sub>

Synonyms:{(NP₃)RhCl₂}BPh₄

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Chemical Property of {(NP₃)RhCl₂}BPh₄

Chemical Property:

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Technology Process of {(NP₃)RhCl₂}BPh₄

There total 2 articles about {(NP₃)RhCl₂}BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 104910-92-1
{((C₆H₅)2PCH₂CH₂)2N(CH₂CH₂P(C₆H₅)(C₆H₄))RhH}⁽¹⁺⁾*(SO₃CF₃)^(1-)={((C₆H₅)2PCH₂CH₂)2N(CH₂CH₂P(C₆H₅)(C₆H₄))RhH}(SO₃CF₃)

: 143-66-8
sodium tetraphenyl borate

: 7782-50-5
chlorine

: 85233-87-0
{(NP₃)RhCl₂}BPh₄

Guidance literature:: In tetrahydrofuran; under N2- or Ar-atmosphere for 5 min. (0°C) Cl2 was bubbled through a soln. of {((Ph2PCH2CH2)2N(CH2CH2PPhC6H4))RhH}(SO3CF3); crystn. by addn. of solid NaBPh4 and EtOH;;
DOI:10.1021/ja00227a022

Reference yield:

: rhodium(III) trichloride hydrate

: 15114-55-3
tris(2-(diphenylphosphino)ethyl)amine

: 143-66-8
sodium tetraphenyl borate

: 85233-87-0
{(NP₃)RhCl₂}BPh₄

Guidance literature:: In ethanol; under N2, solid ligand added to RhCl3*aq soln. in EtOH, refluxed for 4 h, cooled, NaBPh4 in EtOH added; filtered, concd., crystals filtered off, dried in vac., recrystd. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1016/S0020-1693(00)83549-5

Reference yield: 85.0%

: 85233-87-0
{(NP₃)RhCl₂}BPh₄

: 85233-90-5
{(NP₃)RhCl}

Guidance literature:: With NaBH₄; In ethanol; dichloromethane; under N2- or Ar-atmosphere a solution of NaBH4 in ethanol was added portionwise to a soln. of {(NP3)RhCl2}BPh4 in methylene chloride;; elem. anal.;;
DOI:10.1021/ja00227a022