3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

Base Information

Chemical Name:3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene
CAS No.:197726-18-4
Molecular Formula:C₂₅H₃₆F₃NO₂Si
Molecular Weight:467.647
Hs Code.:

Synonyms:3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

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Technology Process of 3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

There total 5 articles about 3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 197726-17-3
1-(3-trifluoroacetylaminophenyl)undec-1E-en-5-yn-3-ol

: 197726-18-4
3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 25 ℃; for 0.5h;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 2809-67-8
oct-2-yne

: 197726-18-4
3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) t-BuLi, 2.) triisopropylborate

2: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

With 1H-imidazole; Triisopropyl borate; tert.-butyl lithium; In N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 53663-37-9
3-aminobenzaldehyde dimethyl acetal

: 197726-18-4
3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Et₃N, 2.) DL-camphorsulfonic acid / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) acetone, 25 deg C, 16 h

2: 1.) NaOMe, 2.) aq. HCl / 1.) DMF, MeOH, 60 deg C, 30 min, 2.) THF, 25 deg C, 1 h

3: 1.) t-BuLi, 2.) triisopropylborate

4: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

With 1H-imidazole; hydrogenchloride; Triisopropyl borate; camphor-10-sulfonic acid; tert.-butyl lithium; sodium methylate; triethylamine; In N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4