3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Base Information

Chemical Name:3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene
CAS No.:197726-19-5
Molecular Formula:C₂₅H₃₈F₃NO₂Si
Molecular Weight:469.663
Hs Code.:

Synonyms:3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Suppliers and Price of 3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

There total 6 articles about 3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 197726-18-4
3-(3-tert-butyldimethylsilyloxyundec-1E-en-5-ynyl)-1-trifluoroacetylaminobenzene

: 197726-19-5
3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Guidance literature:: With quinoline; hydrogen; Pd(2.7 percent Pb)-CaCO₃; In ethanol; at 25 ℃; for 0.5h;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 2809-67-8
oct-2-yne

: 197726-19-5
3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) t-BuLi, 2.) triisopropylborate

2: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

3: 100 percent / H₂, quinoline / 5percent Pd(2.7percent Pb)-CaCO₃ / ethanol / 0.5 h / 25 °C

With 1H-imidazole; quinoline; Triisopropyl borate; hydrogen; tert.-butyl lithium; Pd(2.7 percent Pb)-CaCO₃; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 53663-37-9
3-aminobenzaldehyde dimethyl acetal

: 197726-19-5
3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)-1-trifluoroacetylaminobenzene

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Et₃N, 2.) DL-camphorsulfonic acid / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) acetone, 25 deg C, 16 h

2: 1.) NaOMe, 2.) aq. HCl / 1.) DMF, MeOH, 60 deg C, 30 min, 2.) THF, 25 deg C, 1 h

3: 1.) t-BuLi, 2.) triisopropylborate

4: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

5: 100 percent / H₂, quinoline / 5percent Pd(2.7percent Pb)-CaCO₃ / ethanol / 0.5 h / 25 °C

With 1H-imidazole; quinoline; hydrogenchloride; Triisopropyl borate; camphor-10-sulfonic acid; hydrogen; tert.-butyl lithium; sodium methylate; triethylamine; Pd(2.7 percent Pb)-CaCO₃; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4