2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine

Base Information

Chemical Name:2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine
CAS No.:69498-77-7
Molecular Formula:C₈H₁₈N₂
Molecular Weight:142.244
Hs Code.:
DSSTox Substance ID:DTXSID60989448

Synonyms:69498-77-7;2-(3,3-dimethylbutan-2-ylidene)-1,1-dimethylhydrazine;DTXSID60989448

Suppliers and Price of 2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine

Chemical Property:

Vapor Pressure:1.41mmHg at 25°C
Boiling Point:171.3°C at 760 mmHg
Flash Point:57.4°C
Density:0.8g/cm³
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:142.146998583
Heavy Atom Count:10
Complexity:129

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NN(C)C)C(C)(C)C

Technology Process of 2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine

There total 1 articles about 2-(3,3-Dimethylbutan-2-ylidene)-1,1-dimethylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 75-97-8
3,3-dimethyl-butan-2-one

: 57-14-7
N,N-Dimethylhydrazine

: 69498-77-7
3,3-dimethyl-2-butanone N,N-dimethylhydrazone

Guidance literature:: for 10h; Heating;
DOI:10.1021/jo016058t

Reference yield: 70.0%

: 69498-77-7
3,3-dimethyl-2-butanone N,N-dimethylhydrazone

: 29443-45-6
3,3-Dimethyl-2-butanone hydrazone

Guidance literature:: With hydrazine; In ethanol; for 16h; Heating;
DOI:10.1021/jo00120a013

Reference yield:

: 69498-77-7
3,3-dimethyl-2-butanone N,N-dimethylhydrazone

: 83040-99-7
(E)-8-hydroxy-2,2-dimethyl-8,8-diphenyl-5-octen-3-one

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / LDA / tetrahydrofuran; hexane / 16 h / -78 degC to RT

2: 91 percent / HCl / pentane; H₂O / 0.5 h / Ambient temperature

3: KH, TMEDA, s-BuLi / 2-methyl-butane; tetrahydrofuran / -78 °C

With hydrogenchloride; N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium; potassium hydride; lithium diisopropyl amide; In tetrahydrofuran; methylbutane; hexane; water; pentane;
DOI:10.1016/S0040-4020(01)93280-6