1,2,4-trioxolane, 3-methyl-

Base Information

• Chemical Name: 1,2,4-trioxolane, 3-methyl-
• CAS No.: 38787-96-1
• Molecular Formula: C3H6O3
• Molecular Weight: 90.0788
• Mol file: 38787-96-1.mol

Synonyms:

Chemical Property of 1,2,4-trioxolane, 3-methyl-

Chemical Property:

• Vapor Pressure: 201.04mmHg at 25°C
• Boiling Point: 61.075°C at 760 mmHg
• Density: 1.101g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2,4-trioxolane, 3-methyl-

There total 3 articles about 1,2,4-trioxolane, 3-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → propylene ozonide (38787-96-1) + propylene glycol (57-55-6,63625-56-9) + 2-hydroxypropanal (3913-65-3) + hydroxy-2-propanone (116-09-6) + methyloxirane (75-56-9,16033-71-9) + 2-oxopropanal (78-98-8)

Guidance literature:

With ozone; for 0.00416667h; under 4 Torr; Product distribution; Mechanism; reaction in gas phase; mass spectrum of ozone anf title compound;

DOI:10.1021/ja00403a031

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → propylene ozonide (38787-96-1) + acetaldehyde (75-07-0,9002-91-9) + 4-Methyl-[1,2,3]trioxolane

Guidance literature:

With xenon; ozone; at -223.1 ℃; for 14h; further alkenes, matrices (Freon-13, solid Ar), times and temperatures, labelled ozones (16,18O₃, 18O₃); low temp. ozonolysis in solid Xe and CF₃Cl soln.;

DOI:10.1021/j100220a020

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 1,2,4-trioxolane (289-14-5) + propylene ozonide (38787-96-1) + cis-3,5-Dimethyl-1,2,4-trioxolane (16187-01-2) + trans-3,5-Dimethyl-1,2,4-trioxolane (765-57-1,16187-01-2,16187-15-8)

Guidance literature:

With ozone; acetaldehyde; In various solvent(s); at -78 ℃; Product distribution; further solvents; temperature, solvent, acetaldehyde concentration effects; kinetic secondary isotope effect; percent cis-butene ozonide obtained;

DOI:10.1021/ja00352a030

upstream raw materials:

propene