Technology Process of (phenyl)3Sn(4-amino-3-methyl-1,2,4-triazole-2-thiol(-1H))
There total 2 articles about (phenyl)3Sn(4-amino-3-methyl-1,2,4-triazole-2-thiol(-1H)) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
sodium methoxide;
In
methanol;
byproducts: NaCl; under anhyd. N2 atm.; soln. of ligand in MeOH added to soln. of MeONa inMeOH; mixt. stirred for about 8 h at room temp.; soln. of organotin(IV) triazolate in MeOH added dropwise under stirring (molar ratio 1:2); mix t. stirred for 30-35 h at room temp.; centrifuged; filtered to remove NaCl; volatiles removed (vac.); solid recrystd. (MeOH); elem. anal.;
DOI:10.1016/j.saa.2007.09.009
- Guidance literature:
-
With
sodium methoxide;
In
methanol;
byproducts: NaCl; soln. of ligand in MeOH added to sodium methoxide under dry N2 atm.; mixt. stirred for 8 h at room temp.; soln. of organotin(IV) chloride in MeOH added dropwise with stirring; mixt. stirred for 30-35 h at room temp.; centrifuged; filtered; volatiles removed (vac.); solid recrystd. (MeOH);
DOI:10.1016/j.tca.2009.01.019
- Guidance literature:
-
In
neat (no solvent);
heated in Pt crucible up to 1000°C at heating rate of 10°C/min in dry N2 at flow rate of 400 ml/min; monitored by X-ray diffraction;
DOI:10.1016/j.tca.2009.01.019
