oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato

Base Information

• Chemical Name: oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato
• CAS No.: 65496-72-2
• Molecular Formula: C₄₈H₃₆N₄OTi
• Molecular Weight: 732.72
• Mol file: 65496-72-2.mol

Synonyms:oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato

Chemical Property of oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato

Chemical Property:

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Technology Process of oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato

There total 27 articles about oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(N-i-Pr) + 4-chlorobenzaldehyde (104-88-1) → oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato (65496-72-2)

Guidance literature:

In chloroform-d1; byproducts: p-chlorobenzylidene isopropylamine; (N2); for 20 h at ambient temp.; monitored by NMR; not isolated;

DOI:10.1021/ic990991l

Reference yield: 95.0%

(meso-tetra-p-tolylporphyrinato)Ti=NNMe2 (263151-95-7) + 4-chlorobenzaldehyde (104-88-1) → oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato (65496-72-2)

Guidance literature:

In benzene-d6; byproducts: p-chlorobenzaldehyde N,N-dimethylhydrazone; (N2); overnight at ambient temp.; not isolated, detected by NMR;

DOI:10.1021/ic990991l

Reference yield: 95.0%

(meso-tetra-p-tolylporphyrinato)Ti=NNPh2 (263151-96-8) + 4-chlorobenzaldehyde (104-88-1) → oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato (65496-72-2)

Guidance literature:

In benzene-d6; byproducts: p-chlorobenzaldehyde N,N-diphenylhydrazone; (N2); for 180 h at ambient temp.; monitored by NMR; not isolated;

DOI:10.1021/ic990991l

upstream raw materials:

water

4-chlorobenzaldehyde

Nitrosobenzene

(meso-tetra-p-tolylporphyrinato)Ti=NNMe₂

Downstream raw materials:

(2,3,7,8,12,13,17,18-octaethylporphyrinato)oxotitanium(IV)

(meso-tetra-p-tolylporphyrinato)titanium(III) chloride