(meso-tetra-p-tolylporphyrinato)titanium(III) chloride

Base Information

• Chemical Name: (meso-tetra-p-tolylporphyrinato)titanium(III) chloride
• CAS No.: 129679-90-9
• Molecular Formula: C₄₈H₃₆ClN₄Ti
• Molecular Weight: 752.174
• Mol file: 129679-90-9.mol

Synonyms:(meso-tetra-p-tolylporphyrinato)titanium(III) chloride

Chemical Property of (meso-tetra-p-tolylporphyrinato)titanium(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (meso-tetra-p-tolylporphyrinato)titanium(III) chloride

There total 1 articles about (meso-tetra-p-tolylporphyrinato)titanium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(octaethylporphyrinato)titanium(III) chloride (129679-89-6) + oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato (65496-72-2) → (2,3,7,8,12,13,17,18-octaethylporphyrinato)oxotitanium(IV) (25087-66-5) + (meso-tetra-p-tolylporphyrinato)titanium(III) chloride (129679-90-9)

Guidance literature:

In chloroform-d1; N2-atmosphere; not isolated, reaction followed by NMR spectroscopy;

DOI:10.1021/ic960863m

Reference yield: 66.3%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + (meso-tetra-p-tolylporphyrinato)titanium(III) chloride (129679-90-9) → trans-(meso-tetra-p-tolylporphyrinato)Ti(THF)2 (199998-28-2)

Guidance literature:

With CH₂CHCH₂MgCl; In tetrahydrofuran; toluene; byproducts: allyl radical dimer, MgCl2; absence of air and moisture; dropwise addn. of Grignard reagent (in THF)to Ti-complex (in PhMe) with stirring, standing for 18 h; solvent removal (reduced pressure), extn. into PhMe, filtration (Celite), solvent removal (reduced pressure), trituration with hexanes, solvent removal; can be crystallized (diffusion of hexanes into PhMe soln.); elem. anal.;

Reference yield: 52.0%

(meso-tetra-p-tolylporphyrinato)titanium(III) chloride (129679-90-9) + hex-3-yne (928-49-4) → (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne) (148509-02-8)

Guidance literature:

With NaBEt₃H; In toluene; absence of air and moisture; excess alkyne, stirring at room temp. for 8h; filtration, solvent removal (reduced pressure), dissoln. in PhMe, layering with hexanes, crystn. (-30°C, 6 d; two crops);

upstream raw materials:

(octaethylporphyrinato)titanium(III) chloride

oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato

Downstream raw materials:

(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne)

trans-(meso-tetra-p-tolylporphyrinato)Ti(THF)2