(2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

Base Information

Chemical Name:(2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran
CAS No.:132097-74-6
Molecular Formula:C₄₄H₅₄O₆
Molecular Weight:678.909
Hs Code.:

Synonyms:(2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

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Chemical Property of (2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

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Technology Process of (2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

There total 56 articles about (2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 2216-51-5
(-)-menthol

: C₅₉H₅₃NO₁₀

: C₂₅H₁₉NO₅

: 132097-74-6
(2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

Guidance literature:: With calcium sulfate; [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄]; α,α,α-trifluorotoluene; chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I); In cyclohexane; at -15 ℃; for 24h; stereoselective reaction;
DOI:10.1021/jacs.1c04584

Reference yield: 88.0%

: 2216-51-5
(-)-menthol

: 74808-09-6
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 132097-74-6,132155-06-7
(2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

Guidance literature:: With phenyltrifluorosilane; In dichloromethane; at -40 ℃; for 1h; optical yield given as %de; diastereoselective reaction;
DOI:10.1002/adsc.201100933

Reference yield:

: 2216-51-5
(-)-menthol

: 74808-09-6
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 132097-74-6
(2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

: 132097-74-6,132155-06-7
(2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran

Guidance literature:: With gold(III) chloride; phenylacetylene; In dichloromethane; at 35 - 39 ℃; for 0.166667h; Reagent/catalyst; Overall yield = 85 %; Overall yield = 172 mg; diastereoselective reaction; Molecular sieve;
DOI:10.1002/ejoc.201500137