Vanadium(4+)

Base Information

• Chemical Name: Vanadium(4+)
• CAS No.: 22541-76-0
• Molecular Formula: V
• Molecular Weight: 50.9415
• DSSTox Substance ID: DTXSID50945194
• Wikidata: Q27115175
• Mol file: 22541-76-0.mol

Synonyms:Vanadium(4+);Vanadium, ion(4+);22541-76-0;vanadium(4+) ion;Vanadium 4+;vanadium(IV) cation;Ammonium, triethylhexyl-;CHEBI:33002;DTXSID50945194;Q27115175

Chemical Property of Vanadium(4+)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 50.943958
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [V+4]

Technology Process of Vanadium(4+)

There total 31 articles about Vanadium(4+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.95%

vanadium(5+) (22537-31-1) → vanadium(IV) cation (22541-76-0)

Guidance literature:

With formaldehyd; In sulfuric acid; byproducts: HCOOH; reduction of V(5+) (10 ml of a 0.2 n V(5+) solution (V2O5) in 9 n H2SO4) with 5 ml 1 M HCHO at 25°C within 7 days;;

Reference yield: 43.0%

vanadia → vanadium(IV) cation (22541-76-0)

Guidance literature:

With malonic acid; In sulfuric acid; reduction of V(5+) (10 ml of a 0.2 n V2O5 solution in 13.5 n H2SO4) with 5 ml 0.1 M malonic acid on a water bath within 30 minutes;;

Reference yield:

vanadium (V) oxide * phosphorus (V) oxide * 4 water + potassium bromide (7558-02-3,7758-02-3) → bromine (7726-95-6) + vanadium(IV) cation (22541-76-0)

Guidance literature:

In neat (no solvent);

upstream raw materials:

vanadium

sodium metavanadate

vanadium(II) oxide

hydrogenchloride

Downstream raw materials:

oxo citrato vanadate (IV) (1-)

vanadium⁽⁵⁺⁾