(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

Base Information

Chemical Name:(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one
CAS No.:1429924-66-2
Molecular Formula:C₂₆H₂₈O₄
Molecular Weight:404.506
Hs Code.:

Synonyms:(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

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Chemical Property of (1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

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Technology Process of (1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

There total 1 articles about (1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1002094-23-6
(1R,3R,4R,6R,8R)-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

: 556-56-9
allyl iodid

: 1429924-66-2
(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

Guidance literature:: (1R,3R,4R,6R,8R)-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

allyl iodid; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at -78 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201200376

Reference yield: 90.0%

: 1429924-66-2
(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

: 34164-50-6
4-penten-1-ylmagnesium bromide

: 1429924-71-9
(1S,3R,4R,6R,8R,9R,12R)-9-allyl-6-methoxy-12-(pent-4-en-1-yl)-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodecan-10-one

Guidance literature:: With copper(l) iodide; In tetrahydrofuran; at -78 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201200376

Reference yield: 84.0%

: 1429924-66-2
(1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one

: 75-07-0,9002-91-9
acetaldehyde

: 1429924-67-3
C₃₃H₄₂O₅

Guidance literature:: (1S,3R,4R,6R,8R,9R)-9-allyl-6-methoxy-3,4-diphenyl-2,5-dioxabicyclo[6.4.0]dodec-11-en-10-one; With copper(l) cyanide; 4-penten-1-ylmagnesium bromide; In tetrahydrofuran; at -78 ℃; for 1h;

acetaldehyde; In tetrahydrofuran; at -78 ℃; for 1h;
DOI:10.1002/chem.201200376