(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

Base Information

Chemical Name:(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one
CAS No.:1393833-94-7
Molecular Formula:C₃₃H₂₉NO₄
Molecular Weight:503.598
Hs Code.:

Synonyms:(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

Chemical Property:

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Technology Process of (2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

There total 4 articles about (2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: (4R,E)-3-(4'-benzyloxybut-2'-enoyl)-4,5,5-triphenyloxazolidinone

: 74-88-4
methyl iodide

: 1393833-94-7
(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

: 1393834-02-0
(2'S,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

Guidance literature:: (4R,E)-3-(4'-benzyloxybut-2'-enoyl)-4,5,5-triphenyloxazolidinone; With lithium chloride; In tetrahydrofuran; at -60 ℃; for 0.25h; Inert atmosphere;

With sodium hexamethyldisilazane; In tetrahydrofuran; at -60 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at -45 ℃; for 7h; Reagent/catalyst; stereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2015.05.037

Reference yield:

: C₃₂H₂₇NO₄

: 74-88-4
methyl iodide

: 1393833-94-7
(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

: 1393834-02-0
(2'S,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

Guidance literature:: C₃₂H₂₇NO₄; With potassium hexamethylsilazane; lithium chloride; In tetrahydrofuran; at -60 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at -60 - -45 ℃; for 7h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; optical yield given as %de; diastereoselective reaction; Inert atmosphere; Saturated solution;
DOI:10.1016/j.tetlet.2012.06.133

Reference yield:

: C₃₈H₄₁NO₄Si

: 74-88-4
methyl iodide

: 1393833-94-7
(2'R,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

: 1393834-02-0
(2'S,4R,Z)-N-(4'-benzyloxyl-2-methylbut-3'-enoyl)-4,5,5-triphenyloxazolidin-2-one

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -20 - 20 ℃; Overall yield = 75 %; regioselective reaction;
DOI:10.1016/j.tet.2015.05.037