(S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

Base Information

Chemical Name:(S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide
CAS No.:1023378-00-8
Molecular Formula:C₁₈H₂₅NO₂S
Molecular Weight:319.468
Hs Code.:

Synonyms:(S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

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Chemical Property of (S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

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Technology Process of (S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

There total 2 articles about (S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1165952-92-0
cyclohexa-1,4-diene

: 683226-92-8
(E)-(S)-2-methyl-propane-2-sulfinic acid 1-(4-methoxy-phenyl)-methylideneamide

: 1023377-79-8
(S)-2-methyl-propane-2-sulfinic acid [(S)-(R)-cyclohexa-2,4-dienyl-(4-methoxyphenyl)-methyl]-amide

: 1023378-00-8
(S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

Guidance literature:: cyclohexa-1,4-diene; With N,N,N,N,-tetramethylethylenediamine; (2-methylpropyl)lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;

With magnesium chloride; In tetrahydrofuran; for 3h; Inert atmosphere;

(E)-(S)-2-methyl-propane-2-sulfinic acid 1-(4-methoxy-phenyl)-methylideneamide; In tetrahydrofuran; at -78 ℃; for 0.5h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ol800478q

Reference yield:

: 1165952-92-0
cyclohexa-1,4-diene

: 683226-92-8
(E)-(S)-2-methyl-propane-2-sulfinic acid 1-(4-methoxy-phenyl)-methylideneamide

: (S)-2-methyl-propane-2-sulfinic acid [(R)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

: 1023378-00-8
(S)-2-methyl-propane-2-sulfinic acid [(S)-cyclohexa-2,5-dienyl-(4-methoxy-phenyl)-methyl]-amide

Guidance literature:: cyclohexa-1,4-diene; With N,N,N,N,-tetramethylethylenediamine; (2-methylpropyl)lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; for 3h; Inert atmosphere;

(E)-(S)-2-methyl-propane-2-sulfinic acid 1-(4-methoxy-phenyl)-methylideneamide; In tetrahydrofuran; at -50 ℃; for 72h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ol800478q