(2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite

Base Information

• Chemical Name: (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite
• CAS No.: 462102-52-9
• Molecular Formula: C₃₅H₄₂NO₃P
• Molecular Weight: 555.697
• Mol file: 462102-52-9.mol

Synonyms:(2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite

Chemical Property of (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite

There total 1 articles about (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

di(2,6-dimethoxyphenyl) chlorophosphite (22277-52-7) + (2R)-2-(dibenzylamino)-3-methylbutan-1-ol (372967-45-8) → (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite (462102-52-9)

Guidance literature:

With triethylamine; In benzene; at 50 ℃; for 1h;

DOI:10.1002/1099-0682(200206)2002:6<1367::aid-ejic1367>3.0.co;2-f

Reference yield: 85.0%

di(rhodium)tetracarbonyl dichloride + (2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite (462102-52-9) → RhCl(CO)((2R)-2-(dibenzylamino)-3-methylbutyl bis(2,6-dimethylphenyl) phosphite)

Guidance literature:

With (CH₃COCHCOCH₃)RhCl₂; In dichloromethane; byproducts: CO; under Ar, 2 equiv. of P-compd. in CH2Cl2 was added to CH2Cl2 soln. of (acac)RhCl2 at 20 °C, stirring for 30 min at room temp., 1 equiv. of (Rh(CO)2Cl)2 was added in CH2Cl2, stirring for 1 h; volatiles were removed in vac. (40 Torr), residue was extd. with hexane (four times) and dried in vac. (2 Torr), elem. anal.;

DOI:10.1002/1099-0682(200206)2002:6<1367::aid-ejic1367>3.0.co;2-f

upstream raw materials:

di(2,6-dimethoxyphenyl) chlorophosphite

(2R)-2-(dibenzylamino)-3-methylbutan-1-ol