5,10,15,20-tetrakis(4-iodophenyl)porphyrin

Base Information

• Chemical Name: 5,10,15,20-tetrakis(4-iodophenyl)porphyrin
• CAS No.: 29162-74-1
• Molecular Formula: C₄₄H₂₆I₄N₄
• Molecular Weight: 1118.34
• Mol file: 29162-74-1.mol

Synonyms:5,10,15,20-tetrakis(4-iodophenyl)porphyrin

Chemical Property of 5,10,15,20-tetrakis(4-iodophenyl)porphyrin

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(4-iodophenyl)porphyrin

There total 8 articles about 5,10,15,20-tetrakis(4-iodophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

pyrrole (109-97-7,30604-81-0) + p-(iodophenyl)carboxaldehyde (15164-44-0) → 5,10,15,20-tetrakis(4-iodophenyl)porphyrin (29162-74-1)

Guidance literature:

With propionic acid; for 0.5h; Reflux;

DOI:10.1016/j.saa.2020.118570

Reference yield: 21.0%

pyrrole (109-97-7,30604-81-0) + propionic acid (802294-64-0,79-09-4) + p-(iodophenyl)carboxaldehyde (15164-44-0) → 5,10,15,20-tetrakis(4-iodophenyl)porphyrin (29162-74-1)

Guidance literature:

at 80 ℃; for 1h;

DOI:10.1016/j.molstruc.2021.130601

Reference yield: 17.0%

pyrrole (109-97-7,30604-81-0) + 2,5-bis(α-hydroxy-α-phenylmethyl)thiophene (57546-55-1) + p-(iodophenyl)carboxaldehyde (15164-44-0) → 5,10,15,20-tetrakisphenyl-21,23-dithiaporphyrin (57511-57-6) + 5,10,15,20-tetrakis(4-iodophenyl)porphyrin (29162-74-1) + 5,10-diphenyl-15,20-bis(4-iodophenyl)-21-thiaporphyrin

Guidance literature:

pyrrole; 2,5-bis(α-hydroxy-α-phenylmethyl)thiophene; p-(iodophenyl)carboxaldehyde; With boron trifluoride diethyl etherate; In chloroform; at 20 ℃; for 1h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; for 1h;

DOI:10.1016/S0040-4020(02)00482-9

upstream raw materials:

pyrrole

p-(iodophenyl)carboxaldehyde

tetrakis(4-aminophenyl)porphyrin

mesytaldehyde

Refernces

Exploring crystal structure of 5, 10, 15, 20-tetrakis (4-iodophenyl) porphyrin; H₂TIPP: Experimental and theoretical investigations

10.1016/j.molstruc.2021.130601

Umar Ali Dar and Shakeel A. Shah present a comprehensive study on the synthesis, characterization, and crystal structure analysis of H2TIPP using experimental and theoretical methods. The compound crystallizes in a triclinic system with a planar porphyrin core and twisted phenyl rings. The molecular packing is influenced by various interactions, including intramolecular hydrogen bonding and intermolecular contacts involving N-H, H-H, C-H, C-I, and I-I interactions. The study employs Hirshfeld surface analysis and 2D fingerprint plots to quantify these interactions, revealing significant contributions from H-H, C-H, and C-I contacts. Theoretical calculations using DFT and TD-DFT methods confirm the experimental findings and provide insights into the electronic properties and stability of the compound. The results highlight the potential of H2TIPP as a building block for porous materials and its applications in various fields such as photovoltaics, data storage, and chemical sensing.