C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄

Base Information

• Chemical Name: C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄
• CAS No.: 186205-11-8
• Molecular Formula: BF₄*C₄₉H₄₂IrN₂OP₂
• Molecular Weight: 1015.86

Synonyms:C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄

Chemical Property of C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄

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Technology Process of C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄

There total 2 articles about C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)⁽¹⁺⁾*BF₄^(1-)=[C₁₃H₇N(NH₂)(P(C₆H₅)3)2Ir(H₂O)(H)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2-amino-7,8-benzoquinoline (67410-22-4) + [Ir(1,5-COD)(P(C6H5)3)2]BF4 (38834-40-1) + hydrogen (1333-74-0) → C13H7N(NH2)(P(C6H5)3)2Ir(H2O)(H)(1+)*BF4(1-)=[C13H7N(NH2)(P(C6H5)3)2Ir(H2O)(H)]BF4 (186205-11-8)

Guidance literature:

In dichloromethane; 273°K;

DOI:10.1021/ja9628462

Reference yield: 70.0%

2-amino-7,8-benzoquinoline (67410-22-4) + [Ir(1,5-COD)(P(C6H5)3)2]BF4 (38834-40-1) + hydrogen (1333-74-0) → (2-amino-7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrafluoroborate (186205-11-8)

Guidance literature:

In dichloromethane; Ar or N2-atmosphere; H2-stream (1 atm, 20 ml / min, 5 min, 0°C), concg. (vac.), pptn. on hexanes / Et2O (1 : 1) addn.; filtering, washing (hexanes), drying (vac.); elem. anal.;

DOI:10.1021/om9809769

Reference yield: 65.0%

(2-amino-7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrafluoroborate (186205-11-8) + tetrabutyl ammonium fluoride (429-41-4) → (2-amino-7,8-benzoquinolinato)hydrido(fluoro)bis(triphenylphosphine)iridium(III) (186205-12-9)

Guidance literature:

In acetone; Ar or N2-atmosphere; stirring (10 min), pptn. on hexanes addn.; filtering, washing (hexanes), drying (vac.), recrystn. (CH2Cl2 / hexanes); elem. anal.;

DOI:10.1021/om9809769

upstream raw materials:

2-amino-7,8-benzoquinoline

[Ir(1,5-COD)(P(C₆H₅)3)2]BF₄

hydrogen

Downstream raw materials:

(2-amino-7,8-benzoquinolinato)hydrido(fluoro)bis(triphenylphosphine)iridium(III)

H₂NC₁₃NH₇Ir[P(C₆H₅)3]2H(H₂)⁽¹⁺⁾

[IrH₂(H₃NC₁₃H₇N)(P(C₆H₅)3)2]⁽¹⁺⁾*BF₄^(1-)=[IrH₂(H₃NC₁₃H₇N)(P(C₆H₅)3)2]BF₄

H₂NC₁₃NH₇Ir[P(C₆H₅)3]2H(CO)⁽¹⁺⁾*BF₄^(1-)=H₂NC₁₃NH₇Ir[P(C₆H₅)3]2HCOBF₄

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