[Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂]

Base Information

• Chemical Name: [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂]
• CAS No.: 179612-34-1
• Molecular Formula: C₁₉H₂₄Cl₂N₂Ti
• Molecular Weight: 399.199

Synonyms:[Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂]

Chemical Property of [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂]

Chemical Property:

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Technology Process of [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂]

There total 4 articles about [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(CH3)2C6H3NH2(CH2)3NC6H3(CH3)2TiCl3(1+)*Cl(1-)=(CH3)2C6H3NH2(CH2)3NC6H3(CH3)2TiCl3(Cl) (1106739-96-1) → [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl2] (179612-34-1)

Guidance literature:

With (C₂H₅)3N; In not given; byproducts: (C2H5)3N*HCl; excess of Et3N; yield detected by NMR;

DOI:10.1016/j.ica.2008.02.034

Reference yield: 84.0%

1,3-bis(2,6-dimethylanilino)propane (72991-64-1) + titanium tetrachloride (7550-45-0) → [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl2] (179612-34-1)

Guidance literature:

With (C₂H₅)3N; In toluene; byproducts: (C2H5)3N*HCl; (Ar); soln. of 1,3-(bis(2,6-dimethylanilino)propane in toluene was addedto soln. of TiCl4 ar -78°C, cooling bath was removed, after 15 m in NEt3 was added under vigorous stirring; precipitate was washed with toluene, reduced under vac., cooled to -25°C, crystals was separated, , mother liquor concd., cooled, second batch of crystals was separated;

DOI:10.1016/j.ica.2008.02.034

Reference yield: 81.0%

C3H6(NC8H9Si(CH3)3)2 (179612-32-9) + titanium tetrachloride (7550-45-0) → [Ti(1,3-bis(2,6-dimethylanilino)propane)Cl2] (179612-34-1)

Guidance literature:

In xylene; (N2); reflux in solvent (12 h); filtration (Celite), filtrate volume reduction to slurry, hexane addn. to complete pptn., recrystallization (toluene/hexanes); elem. anal.;

DOI:10.1016/S1381-1169(97)00174-X

upstream raw materials:

C₃H₆(NC₈H₉Si(CH₃)3)2

titanium tetrachloride

1,3-bis(2,6-dimethylanilino)propane

(CH₃)2C₆H₃NH₂(CH₂)3NC₆H₃(CH₃)2TiCl₃⁽¹⁺⁾*Cl^(1-)=(CH₃)2C₆H₃NH₂(CH₂)3NC₆H₃(CH₃)2TiCl₃(Cl)

Downstream raw materials:

[C₃H₆(NC₈H₉)2]Ti(CH₂Si(CH₃)3)2

[C₃H₆(NC₈H₉)2]Ti(CH₂C₆H₅)2

[C6H3(CH3)2N(CH2)3N(CH3)2C6H3]Ti(η-C5H5)Cl

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