[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

Base Information

Chemical Name:[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)
CAS No.:198897-51-7
Molecular Formula:C₄₂H₄₁O₂P₂Ru*F₆P
Molecular Weight:885.768
Hs Code.:

Synonyms:[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

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Chemical Property of [Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

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Technology Process of [Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

There total 3 articles about [Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: [Ru(C₅H₅)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)*99CH₂Cl₂=Ru(C₅H₅)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆*99CH₂Cl₂

: 201230-82-2
carbon monoxide

: 198897-51-7
[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

Guidance literature:: In dichloromethane; High Pressure; stirred for 3 d at room temp. under 65 atm of CO; concd. (vac.), covered (methanol, diethyl ether);
DOI:10.1002/ejic.200501073

Reference yield: 88.0%

: ammonium hexafluorophosphate

: 198897-35-7
RuCl(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))

: 201230-82-2
carbon monoxide

: 198897-51-7
[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

Guidance literature:: In methanol; dichloromethane; CO-atmosphere; stirring soln. of Ru-complex for 1 week, addn. of NH4PF6,stirring overnight; crystn. (CH2Cl2:Et2O);
DOI:10.1021/om970513n

Reference yield: 79.0%

: 198897-39-1
[Ru(η(5)-cyclopentadienyl)(triphenylphosphine)(η(2)(P,O)-Ph2PCH2C(=O)Bu(t))](PF6)*dichloromethane

: 201230-82-2
carbon monoxide

: 198897-51-7
[Ru(CO)(η(5)-cyclopentadienyl)(triphenylphosphine)(η(1)(P)-Ph2PCH2C(=O)Bu(t))](PF6)

Guidance literature:: In methanol; dichloromethane; CO-atmosphere; stirring for 2 weeks; evapn., recrystn. (CH2Cl2:Et2O); elem. anal.;
DOI:10.1021/om970513n