p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside
CAS No.:1023290-63-2
Molecular Formula:C₂₁H₂₄Cl₃NO₈S
Molecular Weight:556.848
Hs Code.:

Synonyms:p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

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Technology Process of p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

There total 1 articles about p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 106-45-6
para-thiocresol

: 219693-02-4
1,3,4,6-tetra-O-acetyl-2-deoxy-2-trichloroacetamido-α/β-D-glucopyranose

: 1023290-63-2
p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

Guidance literature:: With boron trifluoride dimethyl etherate; In dichloromethane; at 20 ℃; Inert atmosphere;
DOI:10.1021/jo9016925

Reference yield:

: 1023290-63-2
p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

: C₁₅H₁₈Cl₃NO₅S

Guidance literature:: With sodium methylate; In methanol; dichloromethane; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1021/jo9016925

Reference yield:

: 1023290-63-2
p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

: 1446762-48-6
5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Molecular sieve

1.2: 0.5 h / 0 °C / Inert atmosphere

2.1: sodium methylate / methanol / 1 h / 20 °C / Inert atmosphere

3.1: camphor-10-sulfonic acid / acetonitrile / 5 h / 0 - 20 °C / Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.17 h / 0 °C / Inert atmosphere

4.2: 0.5 h / 0 °C / Inert atmosphere

5.1: triethylsilane; trifluoroacetic anhydride; trifluoroacetic acid / dichloromethane / 5 h / 0 °C / Inert atmosphere

With triethylsilane; camphor-10-sulfonic acid; sodium methylate; sodium hydride; trifluoroacetic acid; trifluoroacetic anhydride; In methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile; mineral oil;
DOI:10.1002/asia.201201204