5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:1446762-48-6
Molecular Formula:C₂₉H₃₆Cl₃NO₈
Molecular Weight:632.966
Hs Code.:

Synonyms:5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

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Chemical Property of 5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

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Technology Process of 5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 6 articles about 5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1446762-50-0
C₂₉H₃₄Cl₃NO₈

: 1446762-48-6
5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: With triethylsilane; trifluoroacetic acid; trifluoroacetic anhydride; In dichloromethane; at 0 ℃; for 5h; Inert atmosphere;
DOI:10.1002/asia.201201204

Reference yield:

: 1023290-63-2
p-tolyl 3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-1-thio-β-D-glucopyranoside

: 1446762-48-6
5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Molecular sieve

1.2: 0.5 h / 0 °C / Inert atmosphere

2.1: sodium methylate / methanol / 1 h / 20 °C / Inert atmosphere

3.1: camphor-10-sulfonic acid / acetonitrile / 5 h / 0 - 20 °C / Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.17 h / 0 °C / Inert atmosphere

4.2: 0.5 h / 0 °C / Inert atmosphere

5.1: triethylsilane; trifluoroacetic anhydride; trifluoroacetic acid / dichloromethane / 5 h / 0 °C / Inert atmosphere

With triethylsilane; camphor-10-sulfonic acid; sodium methylate; sodium hydride; trifluoroacetic acid; trifluoroacetic anhydride; In methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile; mineral oil;
DOI:10.1002/asia.201201204

Reference yield:

: 1446762-32-8
5-(methoxycarbonyl)pentyl 2-trichloroacetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 1446762-48-6
5-(methoxycarbonyl)pentyl 2-trichloroacetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.17 h / 0 °C / Inert atmosphere

1.2: 0.5 h / 0 °C / Inert atmosphere

2.1: triethylsilane; trifluoroacetic anhydride; trifluoroacetic acid / dichloromethane / 5 h / 0 °C / Inert atmosphere

With triethylsilane; sodium hydride; trifluoroacetic acid; trifluoroacetic anhydride; In dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1002/asia.201201204