(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

Base Information

Chemical Name:(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene
CAS No.:1452161-52-2
Molecular Formula:C₂₉H₄₄O₅Si
Molecular Weight:500.751
Hs Code.:

Synonyms:(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

Chemical Property:

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Technology Process of (6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

There total 3 articles about (6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1452161-51-1
(2S,6S)-1-tert-butyldimethylsilyloxy-4,8-dioxaundeca-10-ene-2,6-diol

: 100-39-0
benzyl bromide

: 1452161-52-2
(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 2h;
DOI:10.3987/COM-12-S(N)67

Reference yield:

: 1452161-58-8
C₉H₁₈O₅

: 1452161-52-2
(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine; dmap / dichloromethane / 23 h / 0 - 20 °C

2: sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

With dmap; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.3987/COM-12-S(N)67

Reference yield:

: 1452161-50-0
(2S,6S)-1,2-O-isopropylidene-4,8-dioxaundeca-10-en-6-ol

: 1452161-52-2
(6S,10S)-11-tert-butyldimethylsilyloxy-6,10-dibenzyloxy-4,8-dioxaundecene

Guidance literature:: Multi-step reaction with 3 steps

1: acetic acid; water / 7 h / 20 °C

2: triethylamine; dmap / dichloromethane / 23 h / 0 - 20 °C

3: sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

With dmap; water; sodium hydride; acetic acid; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.3987/COM-12-S(N)67