pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Base Information

Chemical Name:pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside
CAS No.:915150-26-4
Molecular Formula:C₆₄H₇₈O₁₆Si
Molecular Weight:1131.4
Hs Code.:

pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Synonyms:pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Suppliers and Price of pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

There total 18 articles about pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 915150-25-3
C₆₉H₈₄O₁₈Si

: 915150-26-4
pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Guidance literature:: With pyridine; hydrazine hydrate; acetic acid; In dichloromethane; at 20 ℃; for 0.75h;
DOI:10.1021/jo061233x

Reference yield:

: 1,2-O-(α-allyloxybenzylidene)-β-D-arabinofuranose

: 915150-26-4
pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Guidance literature:: Multi-step reaction with 9 steps

1: 95 percent / NaH / dimethylformamide / 0 - 20 °C

2: p-toluenesulfonic acid / H₂O; 1,2-dimethoxy-ethane / 2 h / 0 - 20 °C

3: 3.71 g / DBU / CH₂Cl₂ / 0.5 h / 0 °C

4: 76 percent / imidazole / dimethylformamide / 6 h / 20 °C

5: 100 percent / 4-(dimethylamino)pyridine; N,N'-dicyclohexylcarbodiimide / CH₂Cl₂ / 1.5 h / 20 °C

6: 99 percent / p-toluenesulfonic acid / 1,2-dimethoxy-ethane / 4 h / 0 - 20 °C

7: 88 percent / DBU / CH₂Cl₂ / 1 h / 0 °C

8: TMSOTf / CH₂Cl₂ / 0.75 h / -40 - -30 °C

9: 5.76 g / acetic acid; pyridine; hydrazine monohydrate / CH₂Cl₂ / 0.75 h / 20 °C

With pyridine; 1H-imidazole; dmap; trimethylsilyl trifluoromethanesulfonate; sodium hydride; toluene-4-sulfonic acid; hydrazine hydrate; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo061233x

Reference yield:

: Benzoic acid (2S,3S,4R,5R)-4-benzyloxy-5-benzyloxymethyl-2-hydroxy-tetrahydro-furan-3-yl ester

: 915150-26-4
pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 3.71 g / DBU / CH₂Cl₂ / 0.5 h / 0 °C

2: 76 percent / imidazole / dimethylformamide / 6 h / 20 °C

3: 100 percent / 4-(dimethylamino)pyridine; N,N'-dicyclohexylcarbodiimide / CH₂Cl₂ / 1.5 h / 20 °C

4: 99 percent / p-toluenesulfonic acid / 1,2-dimethoxy-ethane / 4 h / 0 - 20 °C

5: 88 percent / DBU / CH₂Cl₂ / 1 h / 0 °C

6: TMSOTf / CH₂Cl₂ / 0.75 h / -40 - -30 °C

7: 5.76 g / acetic acid; pyridine; hydrazine monohydrate / CH₂Cl₂ / 0.75 h / 20 °C

With pyridine; 1H-imidazole; dmap; trimethylsilyl trifluoromethanesulfonate; toluene-4-sulfonic acid; hydrazine hydrate; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo061233x