silver tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: silver tetrakis(pentafluorophenyl)borate
• CAS No.: 143607-32-3
• Molecular Formula: Ag*C₂₄BF₂₀
• Molecular Weight: 786.911
• Mol file: 143607-32-3.mol

Synonyms:silver tetrakis(pentafluorophenyl)borate

Chemical Property of silver tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

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Technology Process of silver tetrakis(pentafluorophenyl)borate

There total 2 articles about silver tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

silver fluoride (11113-87-4) + lithium tetrakis(pentafluorophenyl)borate (2797-28-6) → silver tetrakis(pentafluorophenyl)borate (143607-32-3)

Guidance literature:

In dichloromethane; Sonication; (Ar); std. Schlenk technique; suspn. of Li compd. and AgF in CH2Cl2 was sonicated at 40-60°C for 8 h; filtered; solvent removed (vac.); redissolved in hexane; filtered; washed; solvent removed; dried (vac.); elem. anal.;

DOI:10.1021/om901063a

Reference yield: 77.0%

silver nitrate + potassium tetrakis(pentafluorophenyl)borate → silver tetrakis(pentafluorophenyl)borate (143607-32-3)

Guidance literature:

In acetonitrile; for 1h; Glovebox;

Reference yield: 94.0%

1,1,3,3-tetramethylguanidine hydrochloride (1729-17-5) + silver tetrakis(pentafluorophenyl)borate (143607-32-3) → C24BF20(1-)*C5H13N3*H(1+)

Guidance literature:

In dichloromethane; at 25 ℃; for 0.166667h; Darkness;

DOI:10.5560/ZNB.2014-4165

upstream raw materials:

silver fluoride

lithium tetrakis(pentafluorophenyl)borate

Downstream raw materials:

tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

tetrakis(acetonitrile)silver(I) tetrakis(pentafluorophenyl)borate

Ag(benzene)3 tetrakis(pentafluorophenyl)borate

[Cu(2,9-di-tert-butyl-1,10-phenanthroline)2][B(C₆F₅)4]*(dichloromethane)

Refernces

• 1、 Hijazi, Ahmed K.,Taha, Ziyad A.,Ababneh, Taher S.,Alshare, Heba M.,Al-Bataineh, Nezar,Al-Momani, Waleed M.,Ajlouni, Abdulaziz M.. "In vitro biological, catalytic, and DFT studies of some iron(III) N-ligated complexes". . p. 1561 - 1572. Retrieved 2019/12/02.
• 2、 Kuprat, Marcus,Lehmann, Mathias,Schulz, Axel,Villinger, Alexander. "Synthesis of pentafluorophenyl silver by means of lewis acid catalysis: Structure of silver solvent complexes". . p. 1421 - 1427. Retrieved 2010/05/01.