tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate
• CAS No.: 425370-02-1
• Molecular Formula: C₈H₁₂CuN₄*C₂₄BF₂₀
• Molecular Weight: 906.799
• Mol file: 425370-02-1.mol

Synonyms:tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

Chemical Property of tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

There total 4 articles about tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

acetonitrile (75-05-8,26809-02-9) + copper(l) chloride + silver tetrakis(pentafluorophenyl)borate (143607-32-3) → tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate (425370-02-1)

Guidance literature:

In acetonitrile; byproducts: AgCl; (Ar); CuCl added to a soln. of Ag salt, stirred overnight at room temp. in darkness; filtered, concd. (vac.), crystd. at -35°C; elem. anal.;

DOI:10.1016/j.ica.2005.12.044

Reference yield: 75.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + lithium tetrakis(pentafluorophenyl)borate/ethyl ether complex (155543-02-5) → tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate (425370-02-1)

Guidance literature:

In acetonitrile; deaerated CH3CN was added to the mixt. of complexes under Ar flow, stirred for 1 h; degassed H2O was added, ppt. was filtered under Ar, dried under vac. for12 h; elem. anal.;

DOI:10.1021/ic010816g

Reference yield: 61.0%

tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + lithium tetrakis(pentafluorophenyl)borate/ethyl ether complex (155543-02-5) → tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate (425370-02-1)

Guidance literature:

In acetonitrile; deaerated CH3CN was added to the mixt. of complexes under Ar flow, stirred for 30 min; degassed H2O was added, ppt. was filtered under Ar, placed under vac. overnight; elem. anal.;

DOI:10.1021/ic010816g

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

lithium tetrakis(pentafluorophenyl)borate/ethyl ether complex

tetrakis(acetonitrile)copper(I) perchlorate

acetonitrile

Downstream raw materials:

[Cu(I)(CO)(tris(2-pyridylmethyl)amine)][B(C₆F₅)4]

[(3,3′-imino-bis(N,N-dimethylpropylamine))Cu^I][B(C₆F₅)₄]

bis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

[(N-methyl-N,N-bis[3-(dimethylamino)propyl]amine)Cu^I](BAr^F₄)

Refernces

• 1、 Zhang, Yanmei,Sun, Wei,Freund, Christelle,Santos, Ana M.,Herdtweck, Eberhardt,Mink, Janos,Kühn, Fritz E.. "Cationic copper(I) and silver(I) nitrile complexes with fluorinated weakly coordinating anions: Metal-nitrile bond strength and its influence on the catalytic performance". . p. 4723 - 4729. Retrieved 2008/10/09.