Silver fluoride

Base Information

• Chemical Name: Silver fluoride
• CAS No.: 11113-87-4
• Molecular Formula: AgF
• Molecular Weight: 0
• Mol file: 11113-87-4.mol

Synonyms:

Chemical Property of Silver fluoride

Chemical Property:

• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 435℃
• Boiling Point: 19.5°C at 760 mmHg
• PSA: 0.00000
• LogP: 0.00000
• Water Solubility.: 182 g/100 mL (15.5℃)

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Hazard Codes: C:Corrosive
• Statements: R34:
• Safety Statements: S25:; S36/37/39:; S45:

MSDS Files:

Useful:

Technology Process of Silver fluoride

There total 26 articles about Silver fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver(II) fluoride → oxygen (80937-33-3) + silver fluoride (11113-87-4) + ozone (10028-15-6)

Guidance literature:

With water; hydrolytic decomposition;;

DOI:10.1021/ja01334a514

Reference yield:

tetrafluorohydrazine (10036-47-2) + silver nitrate → nitrogen trifluoride (7783-54-2) + silver fluoride (11113-87-4) + dinitrogen tetraoxide (10544-72-6) + nitrosyl fluoride (7789-25-5)

Guidance literature:

In neat (no solvent); 60°C, 18 h;;

DOI:10.1016/0022-1902(66)80107-0

Reference yield:

silver (7440-22-4) + sulfur(VI) hexafluoride (2551-62-4) → sulfur tetrafluoride (7783-60-0) + silver fluoride (11113-87-4)

Guidance literature:

8-14 kV onto Ag wire, in SF6, explosion;

DOI:10.1016/0022-1902(67)80012-5

upstream raw materials:

hydrogen fluoride

chlorine dioxide

silver

silver(l) oxide

Downstream raw materials:

potassium fluoride

cyanogen fluoride

silver hexafluoroantimonate

fluorosilicic acid

Refernces

• 1、 Hilsch, R.,Minnigerode, G. V.,Wartenberg, H. v.. "". . p. 463 - 464. Retrieved 1957.
• 2、 Cook, E. A.,Siegel, B.. "". . p. 2739 - 2743. Retrieved 1967.
• 3、 Bastow,Whitfield,Cockman. "19F NMR IN THE S equals 1/2 ANTIFERROMAGNETS CuF2 AND AgF2.". . p. 325 - 328. Retrieved 1981.
• 4、 Reisinger, Andreas,Himmel, Daniel,Krossing, Ingo. "AgOC(CF3)3 and AgOSiiPr3 - Synthesis and characterization of a donor-free silver(I) alkoxide and silyl oxide". . p. 6997 - 7000. Retrieved 2006.
• 5、 Von Ahsen, Britta,Wartchow, Rudolf,Willner, Helge,Jonas, Volker,Aubke, Friedhelm. "Bis(carbonyl)platinum(II) derivatives: Molecular structure of cis-Pt(CO)2(SO3F)2, complete vibrational analysis of cis-Pt(CO)2Cl2, and attempted synthesis of cis-PT(CO)2F2". . p. 4424 - 4432. Retrieved 2000.
• 6、 Jache, A. W.,Cady, G. H.. "". . p. 1106 - 1109. Retrieved 1952.
• 7、 Stepanova,Gurzhiy,Tyupina,Miroslavov,Sidorenko,Lumpov. "Does [TcF(CO)5] exist? the crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]". . p. 8428 - 8432. Retrieved 2016/06/01.